68979-89-5

Basic information

• Product Name: 2-methylcyclopropan-1-amine
• Synonyms: 2-methylcyclopropan-1-amine
• CAS NO: 68979-89-5
• Molecular Weight: 71.1222
• Mol File: 68979-89-5.mol
• Article Data: 3

Chemical Properties

• CAS DataBase Reference: 2-methylcyclopropan-1-amine(CAS DataBase Reference)
• NIST Chemistry Reference: 2-methylcyclopropan-1-amine(68979-89-5)
• EPA Substance Registry System: 2-methylcyclopropan-1-amine(68979-89-5)

Safety Data

• Hazardous Substances Data: 68979-89-5(Hazardous Substances Data)

Upstream product

• 1759-49-5 (+/-)-cis-<2-Methyl-cyclopropyl>-carbonsaeureamid 
• 29555-02-0 2-methyl-cyclopropanecarboxylic acid 

Downstream Products

• 118539-48-3 (Z)-2-(2,4-Dichloro-5-fluoro-benzoyl)-3-((1R,2S)-2-methyl-cyclopropylamino)-acrylic acid ethyl ester 
• 118539-47-2 (Z)-2-(2,4-Dichloro-5-fluoro-benzoyl)-3-((1R,2R)-2-methyl-cyclopropylamino)-acrylic acid ethyl ester 
• 62869-13-0 2-Chloro-N-(2-chloro-6-methyl-phenyl)-N-[(2-methyl-cyclopropylcarbamoyl)-methyl]-acetamide 
• 62868-89-7 2-Chloro-N-(2,6-dimethyl-phenyl)-N-[(2-methyl-cyclopropylcarbamoyl)-methyl]-acetamide 

Relevant articles and documents

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Modular Access to Substituted Azocanes via a Rhodium-Catalyzed Cycloaddition-Fragmentation Strategy

A short entry to substituted azocanes by a Rh-catalyzed cycloaddition-fragmentation process is described. Specifically, exposure of diverse N-cyclopropylacrylamides to phosphine-ligated cationic Rh(I) catalyst systems under a CO atmosphere enables the directed generation of rhodacyclopentanone intermediates. Subsequent insertion of the alkene component is followed by fragmentation to give the heterocyclic target. Stereochemical studies show, for the first time, that alkene insertion into rhodacyclopentanones can be reversible.