69225-39-4

Basic information

• Product Name: benzene-1,3,5-tricarboxylic acid tri-tert-butyl ester
• Synonyms: benzene-1,3,5-tricarboxylic acid tri-tert-butyl ester
• CAS NO: 69225-39-4
• Molecular Weight: 378.466
• Mol File: 69225-39-4.mol
• Article Data: 6

Chemical Properties

• CAS DataBase Reference: benzene-1,3,5-tricarboxylic acid tri-tert-butyl ester(CAS DataBase Reference)
• NIST Chemistry Reference: benzene-1,3,5-tricarboxylic acid tri-tert-butyl ester(69225-39-4)
• EPA Substance Registry System: benzene-1,3,5-tricarboxylic acid tri-tert-butyl ester(69225-39-4)

Safety Data

• Hazardous Substances Data: 69225-39-4(Hazardous Substances Data)

Upstream product

• 13831-03-3 tert-butyl prop-2-ynoate 
• 4422-95-1 1,3,5-benzene tris(carbonyl chloride) 
• 75-65-0 tert-butyl alcohol 
• 1907-33-1 lithium tert-butoxide 
• 66086-33-7 Di-tert-butyl acetylenedicarboxylate 

Relevant articles and documents

A fast and convenient synthesis of new water-soluble, polyanionic dendrimers

Reasonably simple, efficient, and possessing aspects of generality, the methodology for the synthesis of new, water-soluble, dendrimeric polyesters with great potential applications as antiviral drugs in their own right is described. The essential aspect of the presented approach is a quite unique, immediate access to the polyanionic material at each generation during divergent synthesis. Six target polyanionic dendrimers (generations 1, 2, and 3) have been synthesized. The key monomers applied in this project were 1,3,5-benzenetricarboxylic acid derivatives, which also worked as direct precursors of the charged dendrimer surface.

Cyclotrimerization of phenylacetylene catalyzed by a cobalt half-sandwich complex embedded in an engineered variant of transmembrane protein FhuA

An (η5-cyclopentadienyl)cobalt(i) complex was covalently incorporated into an engineered variant of the transmembrane protein ferric hydroxamate uptake protein component: A, FhuA ΔCVFtev, using a thiol-ene reaction. A CD spectrum shows the structural integrity of the biohybrid catalyst. MALDI-TOF of the segment containing the anchoring site for the cobalt complex Cys545 confirmed successful conjugation. This biohybrid catalyst catalyzed the cyclotrimerization of phenylacetylene to give a mixture of regioisomeric 1,2,4- and 1,3,5-triphenylbenzene in aqueous medium.

Efficient intermolecular [2 + 2 + 2] alkyne cyclotrimerization in aqueous medium using a ruthenium(IV) precatalyst

The dimeric bis(allyl)-ruthenium(IV) complex [{Ru(η3:η3-C10H16)(μ-Cl)Cl}2] (C10H16 = 2,7-dimethylocta-2,6-diene-1,8-diyl) was found to catalyze efficiently the [2 + 2 + 2] cyclization of terminal and internal alkynes in aqueous medium. Copyright