69390-19-8Relevant articles and documents
Curcumin inspired synthesis of unsymmetrical diarylpentanoids with highly potent anti-parasitic activities:: In silico studies and DFT-based stereochemical calculation
Din, Zia Ud,Santos, Alef Dos,Trapp, Marilia Almeida,Lazarin-Bidóia, Danielle,Garcia, Francielle Pelegrin,Peron, Francieli,Nakamura, Celso Vataru,Rodrigues-Filho, Edson
, p. 820 - 831 (2016)
Unsymmetrical diarylpentanoid analogues of curcumin have been synthesized by Claisen-Schmidt condensation of different aldehydes and ketones. Anisaldehyde treated with 2-butanone and chlorobenzaldehyde with 2-pentanone resulted in intermediate compounds 1
Hydroperoxidations of Alkenes using Cobalt Picolinate Catalysts
Peralta-Neel, Zulema,Woerpel
supporting information, p. 5002 - 5006 (2021/06/30)
Hydroperoxides were synthesized in one step from various alkenes using Co(pic)2as the catalyst with molecular oxygen and tetramethyldisiloxane (TMDSO). The hydration product could be obtained using a modified catalyst, Co(3-mepic)2, with molecular oxygen and phenylsilane. Formation of hydroperoxides occurred through a rapid Co-O bond metathesis of a peroxycobalt compound with isopropanol.
Organoseleno-catalyzed synthesis of α,β-unsaturated α′-Alkoxy ketones from allenes enabled by se···o interactions
Toledano-Pinedo, Mireia,Martínez Del Campo, Teresa,Tiemblo, Marta,Fernández, Israel,Almendros, Pedro
, p. 3979 - 3984 (2020/05/14)
α,β-Unsaturated α′-Alkoxy ketones have been prepared under mild conditions from allenes using water as the oxygen source and without the necessity of metals. The organocatalytic oxygenation-rearrangement sequence displays an exquisite chemo-, stereo-, and