7042-36-6

Basic information

• Product Name: TERT-BUTYL CINNAMATE 98
• Synonyms: TERT-BUTYL CINNAMATE 98;TERT-BUTYL CINNAMATE, 99.5%
• CAS NO: 7042-36-6
• Molecular Formula: C₁₃H₁₆O₂
• Molecular Weight: 204.26494
• Mol File: 7042-36-6.mol
• Article Data: 17

Chemical Properties

• Boiling Point: 85 °C0.12 mm Hg(lit.)
• Flash Point: 230 °F
• Appearance: /
• Density: 1 g/mL at 25 °C(lit.)
• CAS DataBase Reference: TERT-BUTYL CINNAMATE 98(CAS DataBase Reference)
• NIST Chemistry Reference: TERT-BUTYL CINNAMATE 98(7042-36-6)
• EPA Substance Registry System: TERT-BUTYL CINNAMATE 98(7042-36-6)

Safety Data

• WGK Germany: 3
• Hazardous Substances Data: 7042-36-6(Hazardous Substances Data)

Upstream product

• 14990-09-1 tert-butyl cinnamate 
• 61501-39-1 (E)-3-Phenyl-2-trimethylsilanyl-acrylic acid tert-butyl ester 
• 131619-47-1 erythro-tert-butyl 3-hydroxy-3-phenyl-2-(trimethylgermyl)propanoate 
• 120823-62-3 tert-butyl (trimethylgermyl)acetate 
• 100-52-7 benzaldehyde 
• 90501-02-3 tert-butyl (tributylstannyl)acetate 
• 140184-83-4 Triphenylstannanyl-acetic acid tert-butyl ester 
• 251904-60-6 tert-butyl 2-(diphenoxyphosphoryl)acetate 
• 86302-43-4 (tert-Butoxycarbonylmethylene)triphenylphosphorane 
• 100-51-6 benzyl alcohol 
• 40052-13-9 mono-tert-butyl malonate 
• 107-59-5 tert-Butyl chloroacetate 
• 5292-43-3 bromoacetic acid tert-butyl ester 
• 1377975-26-2 (tert-butoxycarbonylmethyl)methyldiphenylphosphonium bromide 

Downstream Products

• 143585-06-2 rac-di-tert-butyl (2R,3S)-2-methyl-3-phenylpentanedioate 
• 143585-06-2 di-tert-butyl rac-(2R,3R)-2-methyl-3-phenylpentanedioate 
• 61501-39-1 tert-butyl (Z)-2-trimethylsilylcinnamate 
• 190003-03-3 tert-butyl (3R)-3-(benzylamino)-3-phenylpropanoate 
• 161671-34-7 tert-butyl (R)-3-amino-3-phenylpropionate 
• 95205-95-1 rac-(2R,3S)-2-methyl-3-phenylpentane-1,5-diol 
• 95205-95-1 rac-(2R,3R)-2-methyl-3-phenylpentane-1,5-diol 
• 201804-25-3 t-butyl cis-β-phenylglycidate 
• 132201-33-3 (2R,3S)-N-benzoyl-3-phenylisoserine 

Relevant articles and documents

Carbocation Lewis Acid TrBF4-Catalyzed 1,2-Hydride Migration: Approaches to (Z)-α,β-Unsaturated Esters and α-Branched β-Ketocarbonyls

Carbocation Lewis acid TrBF4-catalyzed 1,2-hydride migration of α-alkyldiazoacetates themselves or in situ-generated cross-coupling adducts of aldehydes and α-alkyldiazoacetates has been developed, affording (Z)-α,β-unsaturated esters and α-branched β-ketocarbonyls, respectively, in good yields and with high regioselectivities.

MYOGLOBIN-BASED CATALYSTS FOR CARBENE TRANSFER REACTIONS

Methods are provided for carrying out carbene transfer transformations such as olefin cyclopropanation reactions, carbene heteroatom-H insertion reactions (heteroatom = N, S, Si), sigmatropic rearrangement reactions, and aldehyde olefination reactions with high efficiency and selectivity by using a novel class of myoglobin-based biocatalysts. These methods are useful for the synthesis of a variety of organic compounds which contain one or more new carbon-carbon or carbon-heteroatom (N, S, or Si) bond. The methods can be applied for conducting these transformations in vitro (i.e., using the biocatalyst in isolated form) and in vivo (i.e., using the biocatalyst in a whole cell system).

Sunlight promoted palladium catalysed Mizoroki-Heck, Suzuki-Miyaura and Sonogashira reactions

The palladium catalysed Mizoroki-Heck, Suzuki-Miyaura and Sonogashira reactions were successfully carried out under irradiation with sunlight. The Heck reaction gives considerable amount of Z product due to photochemical isomerization of initially formed E alkenes. Reaction of methyl 2-iodobenzoate with acrylamide under solar condition furnished 2H-2-benzazepine-1,3-dione rather than the expected derivative of cinnamate while the same reaction with ethyl 2-iodobenzoate gave the desired cinnamide.