712352-08-4 Usage
Description
(+)-N,N-BIS[(1R)-1-PHENYLETHYL]-DINAPHTHO[2,1-D:1',2'-F][1,3,2]DIOXAPHOSPHEPIN-4-AMINE, (11BR) is a complex chiral chemical compound characterized by the presence of two phosphorous atoms and a specific stereochemistry. This unique structure endows it with valuable properties in the realm of organic synthesis and chemical research.
Uses
Used in Asymmetric Catalysis:
(+)-N,N-BIS[(1R)-1-PHENYLETHYL]-DINAPHTHO[2,1-D:1',2'-F][1,3,2]DIOXAPHOSPHEPIN-4-AMINE, (11BR) serves as a crucial ligand in asymmetric catalysis, a technique that is essential for the production of enantiomerically pure compounds. Its role in this process is to facilitate the selective formation of one enantiomer over another, which is particularly important in the pharmaceutical industry where the desired biological activity is often associated with a specific enantiomer.
Used in Organic Synthesis:
In the field of organic synthesis, (+)-N,N-BIS[(1R)-1-PHENYLETHYL]-DINAPHTHO[2,1-D:1',2'-F][1,3,2]DIOXAPHOSPHEPIN-4-AMINE, (11BR) is utilized for the formation of complex organic molecules. Its unique structure allows it to participate in various chemical reactions, contributing to the synthesis of molecules with specific properties and functions that are valuable in a wide range of applications, including pharmaceuticals, agrochemicals, and materials science.
Used in Chemical Research:
(+)-N,N-BIS[(1R)-1-PHENYLETHYL]-DINAPHTHO[2,1-D:1',2'-F][1,3,2]DIOXAPHOSPHEPIN-4-AMINE, (11BR) is also a valuable tool in chemical research, where it can be employed to study reaction mechanisms, explore new synthetic methodologies, and investigate the properties of novel compounds. Its complex structure and chiral nature make it an interesting subject for researchers looking to advance the understanding of chemical processes and develop new technologies.
Check Digit Verification of cas no
The CAS Registry Mumber 712352-08-4 includes 9 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 6 digits, 7,1,2,3,5 and 2 respectively; the second part has 2 digits, 0 and 8 respectively.
Calculate Digit Verification of CAS Registry Number 712352-08:
(8*7)+(7*1)+(6*2)+(5*3)+(4*5)+(3*2)+(2*0)+(1*8)=124
124 % 10 = 4
So 712352-08-4 is a valid CAS Registry Number.
712352-08-4Relevant articles and documents
Enantioselective Allylation of Alkenyl Boronates Promotes a 1,2-Metalate Rearrangement with 1,3-Diastereocontrol
Davis, Colton R.,Luvaga, Irungu K.,Ready, Joseph M.
supporting information, p. 4921 - 4927 (2021/05/04)
Alkenyl boronates add to Ir(π-allyl) intermediates with high enantioselectivity. A 1,2-metalate shift forms a second C-C bond and sets a 1,3-stereochemical relationship. The three-component coupling provides tertiary boronic esters that can undergo multiple additional functionalizations. An extension to trisubstituted olefins sets three contiguous stereocenters.
Development of Axially Chiral Cyclo-Biaryldiol Ligands with Adjustable Dihedral Angles
Zhang, Pengxiang,Yu, Jipan,Peng, Fei,Wu, Xudong,Jie, Jiyang,Liu, Can,Tian, Hua,Yang, Haijun,Fu, Hua
supporting information, p. 17477 - 17484 (2016/11/23)
A new type of axially chiral cyclo-[1,1′-biphenyl]-2,2′-diol (CYCNOL) ligands with adjustable dihedral angles have been developed by varying the bridge chain length. Eight-, nine- and ten-membered cyclo-ligands were prepared and evaluated by using two representative examples: enantioselective additions of diethylzinc to aldehydes and organometallic reagents to enones. The results revealed that the fine regulation of dihedral angles through variation of the bridge chain length was effective in the asymmetric synthesis.
(R)-2,2’-Binaphthoyl-(S,S)-di(1-phenylethyl) aminophosphine. Scalable protocols for the syntheses of phosphoramidite (feringa) ligands
Smith, Craig R.,Mans, Daniel J.,RajanBabu,Denmark, Scott E.,Nguyen, T.
, p. 238 - 247 (2017/09/23)
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