71443-23-7Relevant articles and documents
Silica gel enables Achmatowicz rearrangement with KBr/oxone under “anhydrous” condition for one-pot functionalization
Zhao, Guodong,Tong, Rongbiao
, p. 1669 - 1675 (2019/01/04)
Silica gel was found to effectively promote Achmatowicz rearrangement (AchR) using KBr/oxone under near anhydrous condition. This new protocol allows direct functionalization of AchR products in a one-pot manner, effectively reducing the cost, time, and e
De novo asymmetric bio- and chemocatalytic synthesis of saccharides - Stereoselective formal O-glycoside bond formation using palladium catalysis
Comely, Alex C.,Eelkema, Rienk,Minnaard, Adriaan J.,Feringa, Ben L.
, p. 8714 - 8715 (2007/10/03)
A novel integrated bio- and chemocatalytic approach to the de novo catalytic asymmetric synthesis of saccharides has been developed. Acetoxypyranones obtained enantiopure by enzymatic resolution have been shown to undergo highly stereoselective palladium-catalyzed formal O-glycoside bond formation. The combination of these protocols can be applied to the iterative asymmetric catalytic synthesis of saccharides. Copyright
Montmorillonite K-10 clay catalysed glycosidation of 1-O-acetyl-2,3-dideoxy-DL-pent-2-enopyrano-4-ulose
Shanmugam,Nair
, p. 3007 - 3013 (2007/10/03)
The O-glycosidation reaction of 1-O-acetyl-2,3-dideoxy-DL-pent-2-enopyran-4-ulose catalysed by the environmentally accepted and inexpensive industrial catalyst Montmorillonite K-10 clay with variety of alcohols in high yield is reported.