71479-08-8

Basic information

• Product Name: 4-Hexen-3-one, 2,2-dimethyl-5-phenyl-
• CAS NO: 71479-08-8
• Molecular Formula: C14H18O
• Molecular Weight: 202.296
• Mol File: 71479-08-8.mol
• Article Data: 2

Chemical Properties

• CAS DataBase Reference: 4-Hexen-3-one, 2,2-dimethyl-5-phenyl-(CAS DataBase Reference)
• NIST Chemistry Reference: 4-Hexen-3-one, 2,2-dimethyl-5-phenyl-(71479-08-8)
• EPA Substance Registry System: 4-Hexen-3-one, 2,2-dimethyl-5-phenyl-(71479-08-8)

Safety Data

• Hazardous Substances Data: 71479-08-8(Hazardous Substances Data)

Upstream product

• 17510-46-2 3,3-dimethyl-2-(trimethylsilyl)oxy-1-butene 
• 98-86-2 acetophenone 
• 30263-65-1 1,1-dibromo-3,3-dimethylbutan-2-one 

Downstream Products

• 80562-41-0 (2-tert-Butyl-6-furan-2-yl-2-hydroxy-4-phenyl-cyclohex-3-enyl)-phenyl-methanone 
• 80547-30-4 (2-tert-Butyl-4,6-diphenyl-cyclohexa-2,4-dienyl)-thiophen-2-yl-methanone 
• 80547-27-9 (2-tert-Butyl-4,6-diphenyl-cyclohexa-2,4-dienyl)-phenyl-methanone 
• 80547-28-0 1-(2-tert-Butyl-4,6-diphenyl-cyclohexa-2,4-dienyl)-2,2-dimethyl-propan-1-one 
• 80547-22-4 1-(2-tert-Butyl-2-hydroxy-4,6-diphenyl-cyclohex-3-enyl)-2,2-dimethyl-propan-1-one 
• 80547-25-7 (2-tert-Butyl-2-hydroxy-4,6-diphenyl-cyclohex-3-enyl)-thiophen-2-yl-methanone 
• 80547-20-2 (2-tert-Butyl-2-hydroxy-4,6-diphenyl-cyclohex-3-enyl)-phenyl-methanone 

Relevant articles and documents

Mukaiyama aldol reactions catalyzed by a trimeric organo aluminum(III) alkoxide

Mukaiyama aldol reactions of enol ethers with a variety of aldehydes and ketones are efficiently catalyzed at 0-25 °C by the sterically bulky trimeric organo aluminum(III) alkoxide 1 synthesized via the reaction of 3 equiv of AlMe3 with tripodal tris(2-hydroxy-3-tert-butyl-5-methylphenyl) methane and the elimination of 3 equiv of methane. Comparisons of its catalytic properties with the less sterically hindered analogue 2, the more sterically hindered analogue 3, a monomeric aluminum near-analogue 4, and a dimeric alumatrane 5 revealed that 1 possesses superior activity.