71832-02-5

Basic information

• Product Name: Benzenemethanol, a-phenyl-a-(2-phenylethenyl)-, (E)-
• CAS NO: 71832-02-5
• Molecular Formula: C21H18O
• Molecular Weight: 286.373
• Mol File: 71832-02-5.mol
• Article Data: 13

Chemical Properties

• CAS DataBase Reference: Benzenemethanol, a-phenyl-a-(2-phenylethenyl)-, (E)-(CAS DataBase Reference)
• NIST Chemistry Reference: Benzenemethanol, a-phenyl-a-(2-phenylethenyl)-, (E)-(71832-02-5)
• EPA Substance Registry System: Benzenemethanol, a-phenyl-a-(2-phenylethenyl)-, (E)-(71832-02-5)

Safety Data

• Hazardous Substances Data: 71832-02-5(Hazardous Substances Data)

Upstream product

• 1623-99-0 phenyl sodium 
• 103-26-4 methyl cinnamate 
• 1522-13-0 1,1,3-triphenylprop-2-yn-1-ol 
• 3376-23-6 C-phenyl-N-methylnitrone 
• 119-61-9 benzophenone 
• 3923-52-2 1,1-diphenyl-2-propyn-1-ol 
• 98-80-6 phenylboronic acid 
• 94-41-7 benzalacetophenone 
• 100-58-3 phenylmagnesium bromide 
• 100-52-7 benzaldehyde 
• 98-86-2 acetophenone 
• 591-51-5 phenyllithium 
• 614-47-1 1,3-diphenyl-propen-3-one 
• 19367-33-0 2-Methyl-3,5,5-triphenylisoxazolidine 

Downstream Products

• 62214-54-4 1-methoxy-1-1.3t-triphenyl-propene-⁽²⁾ 
• 91-01-0 1,1-Diphenylmethanol 
• 103-30-0 (E)-1,2-diphenyl-ethene 
• 737-79-1 1,1,3,-triphenyl-1-propene 
• 136859-88-6 1,1,3-triphenylprop-2-enyl acetate 
• 1398654-72-2 (E)-(1-((3-phenylprop-2-yn-1-yl)oxy)prop-2-ene-1,1,3-triyl)tribenzene 
• 1398654-91-5 (1S,6R,7R)-2,2,6,7-tetraphenyl-3-oxabicyclo[4.1.0]hept-4-ene 
• 6817-43-2 hexa-1,5-diene-1,1,3,4,6,6-hexaylhexabenzene 
• 1322700-99-1 C₃₃H₃₀ 
• 1322700-89-9 C₃₉H₃₄ 
• 1322700-87-7 C₃₇H₂₈Cl₂ 
• 1322700-92-4 C₃₉H₃₄O₂ 
• 1322700-93-5 C₃₉H₃₆O₃ 
• 1322700-95-7 C₃₂H₂₈ 

Relevant articles and documents

Synthetic and mechanistic studies in enantioselective allylic substitutions catalysed by palladium complexes of a modular class of axially chiral quinazoline-containing ligands

The application of palladium complexes of a modular series of axially chiral phosphinamine ligands, the Quinazolinaps, to the enantioselective alkylation of 1,3-diphenyl-2-propenyl acetate with dimethyl malonate and methyl dimethyl malonate is described.

One-point binding ligands for asymmetric gold catalysis: Phosphoramidites with a TADDOL-related but acyclic backbone

Readily available phosphoramidites incorporating TADDOL-related diols with an acyclic backbone turned out to be excellent ligands for asymmetric gold catalysis, allowing a number of mechanistically different transformations to be performed with good to outstanding enantioselectivities. This includes [2 + 2] and [4 + 2] cycloadditions of ene-allenes, cycloisomerizations of enynes, hydroarylation reactions with formation of indolines, as well as intramolecular hydroaminations and hydroalkoxylations of allenes. Their preparative relevance is underscored by an application to an efficient synthesis of the antidepressive drug candidate (-)-GSK 1360707. The distinctive design element of the new ligands is their acyclic dimethyl ether backbone in lieu of the (isopropylidene) acetal moiety characteristic for traditional TADDOLs. Crystallographic data in combination with computational studies allow the efficiency of the gold complexes endowed with such one-point binding ligands to be rationalized.