71864-40-9Relevant articles and documents
Nucleophilic carbene-mediated hydrophosphonylation of aldimines
Cai, Zhi-Hua,Du, Guang-Fen,Dai, Bin,He, Lin
supporting information; experimental part, p. 694 - 698 (2012/04/10)
Aldimines undergo efficient hydrophosphonylation reactions with dimethyl phosphite in the presence of nucleophilic heterocyclic- carbenes (NHCs) as organocatalysts to give the corresponding (α-aminoalkyl)phosphonates in moderate-to-excellent yields. Georg
Highly efficient synthesis of functionalized tertiary alcohols catalyzed by potassium alkoxide-crown ether complexes
Hatano, Manabu,Suzuki, Shinji,Takagi, Eri,Ishihara, Kazuaki
supporting information; experimental part, p. 3171 - 3174 (2009/08/09)
A highly efficient Mukaiyama aldol reaction between ketones and trimethylsilyl enolates in the presence of potassium alkoxide-crown ether complexes as Lewis base catalysts (0.3-5 mol %), which minimized the competing retro-aldol reaction, was developed. T