71921-02-3

Basic information

• Product Name: 2-benzyl-2-formamidoacetic acid methyl ester
• Synonyms: 2-benzyl-2-formamidoacetic acid methyl ester
• CAS NO: 71921-02-3
• Molecular Weight: 207.229
• Mol File: 71921-02-3.mol
• Article Data: 16

Chemical Properties

• CAS DataBase Reference: 2-benzyl-2-formamidoacetic acid methyl ester(CAS DataBase Reference)
• NIST Chemistry Reference: 2-benzyl-2-formamidoacetic acid methyl ester(71921-02-3)
• EPA Substance Registry System: 2-benzyl-2-formamidoacetic acid methyl ester(71921-02-3)

Safety Data

• Hazardous Substances Data: 71921-02-3(Hazardous Substances Data)

Upstream product

• 186581-53-3 diazomethane 
• 64-18-6 formic acid 
• 150-30-1 Phenylalanine 
• 103884-33-9 cinnamic formic anhydride 
• 5619-07-8 methyl 2-amino-3-phenylpropanoate hydrochloride 
• 103884-32-8 formic 4-methoxybenzoic anhydride 
• 15028-44-1 DL-phenylalanine methyl ester 
• 65638-74-6 (Z)-N-Formyldehydrophenylalanin-methylester 
• 2258-42-6 formyl acetic anhydride 
• 109-94-4 formic acid ethyl ester 
• 150760-95-5 formic acid cyanomethyl ester 
• 136745-06-7 2-[2-(2,2-Dimethyl-propionylamino)-eth-(E)-ylideneamino]-3-phenyl-propionic acid methyl ester 
• 103871-42-7 2-{3-[(2,2-Dimethyl-propionylamino)-methyl]-oxaziridin-2-yl}-3-phenyl-propionic acid methyl ester 
• 18197-22-3 N-formylformamide 

Downstream Products

• 120301-84-0 N-Cyclopropyl-2-formylamino-3-phenyl-propionamide 
• 120301-86-2 N-(1-Benzyl-2-oxo-2-piperidin-1-yl-ethyl)-formamide 
• 120301-85-1 N-Cyclopentyl-2-formylamino-3-phenyl-propionamide 
• 85059-51-4 2-isocyano-3-phenyl-1-(pyrrolidin-1-yl)propan-1-one 
• 120301-87-3 N-(1-benzyl-2-morpholin-4-yl-2-oxo-ethyl)formamide 
• 85059-38-7 2-isocyano-3-phenyl-1-(piperidin-1-yl)propan-1-one 
• 120301-88-4 N-Cyclohexyl-2-formylamino-N-methyl-3-phenyl-propionamide 
• 85059-48-9 2-isocyano-1-morpholin-4-yl-3-phenylpropan-1-one 

Relevant articles and documents

Synthesis of a novel category of pseudo-peptides using an Ugi three-component reaction of levulinic acid as bifunctional substrate, amines, and amino acid-based isocyanides

The synthesis of a novel category of pseudo-peptides via intramolecular Ugi reaction of levulinic acid (4-oxopentanoic acid), aromatic and aliphatic amines, and amino acid-based isocyanides is reported. Levulinic acid was applied as a bifunctional substrate containing both carbonyl and acid moieties suitable for the Ugi reaction. This article provides a facile and convenient one-pot procedure for the synthesis of peptide-like heterocyclic molecules containing 2-pyrrolidone (γ-lactam), amide and ester functional groups with good to excellent yields.

ANTIFOULING AGENT FOR UNDERWATER ADHERING ORGANISMS HAVING AMINO ACID ISONITRILE SKELETON

PROBLEM TO BE SOLVED: To provide a novel antifouling agent for underwater adhering organisms having excellent characteristics compared with well-known antifouling agents. SOLUTION: An antifouling agent for underwater adhering organisms comprises a compound represented by formula (I) or salt thereof, or solvate thereof, as an active ingredient. COPYRIGHT: (C)2015,JPO&INPIT

The Role of the Amino Protecting Group during Parahydrogenation of Protected Dehydroamino Acids

A series of dehydroamino acids endowed with different protective groups at the amino and carboxylate moieties and with different substituents at the double bond have been reacted with parahydrogen. The observed ParaHydrogen Induced Polarization (PHIP) effects in the 1H NMR spectra are strongly dependent on the amino protecting group. DFT calculations allowed us to establish a relationship between the structures of the reaction intermediates (whose energies depend on the amido substitution) and the observed PHIP patterns.