72142-85-9

Basic information

• Product Name: 2-Phenyl-naphtho<1,2-d>thiazol
• Synonyms: 2-Phenyl-naphtho<1,2-d>thiazol
• CAS NO: 72142-85-9
• Molecular Weight: 261.347
• Mol File: 72142-85-9.mol
• Article Data: 17

Chemical Properties

• CAS DataBase Reference: 2-Phenyl-naphtho<1,2-d>thiazol(CAS DataBase Reference)
• NIST Chemistry Reference: 2-Phenyl-naphtho<1,2-d>thiazol(72142-85-9)
• EPA Substance Registry System: 2-Phenyl-naphtho<1,2-d>thiazol(72142-85-9)

Safety Data

• Hazardous Substances Data: 72142-85-9(Hazardous Substances Data)

Upstream product

• 78569-36-5 (E)-N-(naphthalen-1-yl)-1-phenylmethanimine 
• 134-32-7 1-amino-naphthalene 
• 100-52-7 benzaldehyde 
• 100-46-9 benzylamine 
• 28353-74-4 3,4-dihydronaphthalen-1(2H)-one O-acetyl oxime 
• 86-57-7 1-Nitronaphthalene 
• 100-51-6 benzyl alcohol 
• 98-88-4 benzoyl chloride 
• 100-58-3 phenylmagnesium bromide 
• 551-06-4 1-isothiocyanatonaphthalene 
• 108-88-3 toluene 
• 96963-47-2 N-(naphthalen-1-yl)benzothioamide 
• 634-42-4 N-1-naphthalenyl-benzamide 

Downstream Products

• 63512-54-9 1-aminonaphthalene-2-thiol 

Relevant articles and documents

Graphene oxide-catalyzed synthesis of benzothiazoles with amines and elemental sulfur via oxidative coupling strategy of amines to imines

The graphene oxide-catalyzed coupling and cyclization reactions of primary amines with elemental sulfur was developed to afford various optically property benzothiazoles. This coupling and cyclization strategies proceeded under the oxidant system graphene oxide/O2 and constructed carbon-heteroatom (N, S) bonds with amines and elemental sulfur. Due to benzothiazoles as common chromophores, these products exhibited intriguing fluorescence properties, including outstanding Stokes shifts (up to 161 nm) and quantum yields (up to 74%). Utilizing the products’ unique fluorescence response in different solvents, β-naphthothiazole 4a showed excellent aggregation-induced emission properties in 1,2-dichloroethane, which was 60 times higher than in tetrahydrofuran.

Riboflavin as Photoredox Catalyst in the Cyclization of Thiobenzanilides: Synthesis of 2-Substituted Benzothiazoles

Benzothiazoles are synthesized from thiobenzanilides using riboflavin as a photosensitizer and potassium peroxydisulfate as a sacrificial oxidizing agent under visible light irradiation. The methodology accepts a broad range of functional groups and affords the 2-substituted benzothiazoles by transition-metal-free organic photoredox catalysis under very mild conditions.

Iron-Promoted Three-Component 2-Substituted Benzothiazole Formation via Nitroarene ortho-C-H Sulfuration with Elemental Sulfur

A three-component procedure for the preparation of 2-substituted benzothiazoles from nitroarenes, alcohols, and sulfur powder is described. The reaction showed a good functional group tolerance to provide the heterocyclic products in moderate to good yields. The sequential assembly involving nitro reduction, C-N condensation, and C-S bond formation has been realized in one pot.