78569-36-5Relevant articles and documents
New insight into the nature of electron delocalization: The driving forces for distorting the geometry of stilbene-like species
Yu, Zhong-Heng,Peng, Xiao-Qi
, p. 8541 - 8553 (2001)
To understand the nature of electron delocalization while questioning the abnormally large torsional angle θ of N-phenylmethylene-3-pyridineamine (6), we greatly improved our new program for energy partitioning. Meanwhile, the crystal structures of N-phen
Synergistic Photoredox Catalysis and Organocatalysis for Inverse Hydroboration of Imines
Zhou, Nengneng,Yuan, Xiang-Ai,Zhao, Yue,Xie, Jin,Zhu, Chengjian
supporting information, p. 3990 - 3994 (2018/03/21)
The first catalytic inverse hydroboration of imines with N-heterocyclic carbene (NHC) boranes has been realized by means of cooperative organocatalysis and photocatalysis. This catalytic combination provides a promising platform for promoting NHC-boryl radical chemistry under sustainable and radical-initiator-free conditions. The highly important functional-group compatibility and possible application in late-stage hydroborations represent an important step forward to an enhanced α-amino organoboron library.
Combination of Enabling Technologies to Improve and Describe the Stereoselectivity of Wolff-Staudinger Cascade Reaction
Musio,Mariani,?liwiński,Kabeshov,Odajima,Ley
supporting information, p. 3515 - 3526 (2016/10/18)
A new, single-mode bench-top resonator was evaluated for the microwave-assisted flow generation of primary ketenes by thermal decomposition of α-diazoketones at high temperature. A number of amides and β-lactams were obtained by ketene generation in situ and reaction with amines and imines, respectively, in good to excellent yields. The preferential formation of trans-configured β-lactams was observed during the [2+2] Staudinger cycloaddition of a range of ketenes with different imines under controlled reaction conditions. Some insights into the mechanism of this reaction at high temperature are reported, and a new web-based molecular viewer, which takes advantage from Augmented Reality (AR) technology, is also described for a faster interpretation of computed data.