72485-37-1

Basic information

• Product Name: (4R^*,6S^*,7S^*)-7-acetyloxy-4,6-dimethyl-3-nonanone
• CAS NO: 72485-37-1
• Molecular Weight: 228.332
• Mol File: 72485-37-1.mol
• Article Data: 11

Chemical Properties

• CAS DataBase Reference: (4R^*,6S^*,7S^*)-7-acetyloxy-4,6-dimethyl-3-nonanone(CAS DataBase Reference)
• NIST Chemistry Reference: (4R^*,6S^*,7S^*)-7-acetyloxy-4,6-dimethyl-3-nonanone(72485-37-1)
• EPA Substance Registry System: (4R^*,6S^*,7S^*)-7-acetyloxy-4,6-dimethyl-3-nonanone(72485-37-1)

Safety Data

• Hazardous Substances Data: 72485-37-1(Hazardous Substances Data)

Upstream product

• 108-24-7 acetic anhydride 
• 86421-21-8 (4RS,6S,7S)-Serricornin 
• 72598-35-7 (-)-serricornin 
• 72522-40-8 (4R,6S,7S)-7-hydroxy-4,6-dimethyl-3-nonanone 
• 85593-51-7 (S)-2-((1S,3S)-3-[1,3]Dithian-2-yl-1-methyl-butyl)-oxirane 
• 85593-48-2 1,6-anhydro-2,3,4-trideoxy-4-C-methyl-2-C-methylene-β-D-erythro-hexopyranoside 
• 63000-65-7 <1S,2S,5S>-2-methyl-6,8-dioxabicyclo<3,2,1>octa-4-one 
• 91660-58-1 (3R,5R,6S)-2,6-Diethyl-3,5-dimethyl-tetrahydro-pyran-2-ol 
• 92927-33-8 (4R^*,6R^*,7S^*)-3,3-ethylenedioxy-7-hydroxy-4,6-dimethyl-3-nonanone 
• 92927-32-7 (4R^*,6R^*,7S^*)-7-acetyloxy-3,3-ethylenedioxy-4,6-dimethyl-3-nonanone 
• 91660-58-1 (3R,5S,6R)-2,6-Diethyl-3,5-dimethyl-tetrahydro-pyran-2-ol 
• 92927-33-8 (4R^*,6S^*,7R^*)-3,3-ethylenedioxy-7-hydroxy-4,6-dimethyl-3-nonanone 
• 92927-32-7 (4R^*,6S^*,7R^*)-7-acetyloxy-3,3-ethylenedioxy-4,6-dimethyl-3-nonanone 
• 82290-61-7 2-[(1S,3S,4S)-4-(1-Ethoxy-ethoxy)-1,3-dimethyl-hexyl]-[1,3]dithiane 

Downstream Products

• 72485-37-1 (4R^*,6S^*,7S^*)-7-acetyloxy-4,6-dimethyl-3-nonanone 
• 72485-37-1 (4R^*,6R^*,7R^*)-7-acetyloxy-4,6-dimethyl-3-nonanone 

Relevant articles and documents

Synthesis of (4R,6S,7R)-7-hydroxy-4,6-dimethyl-3-nonanone and (3R,5S,6R)-6-hydroxy-3,5-dimethyl-2-octanone

The synthesis of (4R,6S,7R)-7-hydroxy-4,6-dimethyl-3-nonanone and (3R,5S,6R)-6-hydroxy-3,5-dimethyl-2-octanone is described as their acetates using a desymmetrization strategy as well as an Evans syn aldol strategy.

Synthesis of (4R,6S,7R)-7-hydroxy-4,6-dimethyl-3-nonanone and (3R,5S,6R)-6-hydroxy-3,5-dimethyl-2-octanone, the pheromone components of the bostrychid beetle, Dinoderus bifoveolatus

(4R,6S,7R)-7-Hydroxy-4,6-dimethyl-3-nonanone and (3R,5S,6R)-6-hydroxy-3,5- dimethyl-2-octanone, the pheromone components of the bostrychid beetle, Dinoderus bifoveolatus, as well as their (4R,6S,7S)-and (3R,5S,6S)-isomers were synthesized from (2R,4S,5R)- and (2R,4S,5S)2,4-dimethyl-5-heptanolide, respectively.

AN EFFICIENT AND STEREOSELECTIVE TOTAL SYNTHESIS OF (+/-)-SERRICORNINE

An efficient and stereoselective total synthesis of (+/-)-serricornine (1) the sex pheromone produced by the female cigarette beetle Lasioderma serricorne F, is described. (3SR,5SR,6SR)-6-Ethyltetrahydro-3,5-dimethyl-2H-pyran-2-one (10) is prepared in 65percent yield through lactonization of a 1:1 mixture of C-2 epimrs of the corresponding esters.