73891-04-0

Basic information

• Product Name: 2,3,6-tridesoxy-4-O-p-nitrobenzoyl-3-(trifluoroacetamido)-L-arabino-hex-1-enitol
• Synonyms: 2,3,6-tridesoxy-4-O-p-nitrobenzoyl-3-(trifluoroacetamido)-L-arabino-hex-1-enitol
• CAS NO: 73891-04-0
• Molecular Weight: 374.273
• Mol File: 73891-04-0.mol
• Article Data: 2

Chemical Properties

• CAS DataBase Reference: 2,3,6-tridesoxy-4-O-p-nitrobenzoyl-3-(trifluoroacetamido)-L-arabino-hex-1-enitol(CAS DataBase Reference)
• NIST Chemistry Reference: 2,3,6-tridesoxy-4-O-p-nitrobenzoyl-3-(trifluoroacetamido)-L-arabino-hex-1-enitol(73891-04-0)
• EPA Substance Registry System: 2,3,6-tridesoxy-4-O-p-nitrobenzoyl-3-(trifluoroacetamido)-L-arabino-hex-1-enitol(73891-04-0)

Safety Data

• Hazardous Substances Data: 73891-04-0(Hazardous Substances Data)

Upstream product

• 76739-66-7 3,4-di-O-acetyl-D-rhamnal 
• 61819-51-0 methyl-4-O-benzoyl-2,3,6-tridesoxy-α-D-threo-hex-2-enopyranoside 
• 73864-37-6 3-amino-1,5-anhydro-2,3,6-tridesoxy-D-xylo-hex-1-enitol 
• 33648-04-3 methyl-4-O-acetyl-2,3,6-tridesoxy-α-D-threo-hex-2-enopyranoside 
• 33648-00-9 methyl-2,3,6-tridesoxy-α-D-threo-hex-2-enopyranoside 
• 33647-98-2 methyl-2,3,6-tridesoxy-α-D-erythro-hex-2-enopyranoside 
• 122-04-3 4-nitro-benzoyl chloride 
• 76793-56-1 1,5-anhydro-2,3,6-tridesoxy-3-trifluoroacetamido-D-xylo-hex-1-enitol 
• 73864-37-6 3-amino-1,5-anhydro-2,3,6-tridesoxy-D-arabino-hex-1-enitol 
• 407-25-0 trifluoroacetic anhydride 
• 14218-08-7 2,3,4-tri-O-benzoyl-α-L-rhamnopyranosyl bromide 
• 73864-37-6 3-amino-1,5-anhydro-2,3,6-tridesoxy-L-arabino-hex-1-enitol 
• 34820-21-8 1,5-anhydro-3,4-di-O-benzoyl-2,6-didesoxy-L-arabino-hex-1-enitol 
• 73864-38-7 2,3,6-tridesoxy-3-(trifluoroacetamido)-L-arabino-hex-1-enitol 

Downstream Products

• 128135-66-0 4-Nitro-benzoic acid (2S,3R,4S,6S)-6-[(2S,3S,4S,6R)-6-benzyloxy-2-methyl-4-(2,2,2-trifluoro-acetylamino)-tetrahydro-pyran-3-yloxy]-2-methyl-4-(2,2,2-trifluoro-acetylamino)-tetrahydro-pyran-3-yl ester 
• 128164-28-3 C₃₈H₄₁F₉N₄O₁₃ 
• 128240-82-4 4-Nitro-benzoic acid (2S,3R,4S,6R)-6-benzyloxy-2-methyl-4-(2,2,2-trifluoro-acetylamino)-tetrahydro-pyran-3-yl ester 
• 57918-24-8 4’-epidaunorubicin 
• 73864-40-1 cyclohexyl-2,3,6-tridesoxy-4-O-p-nitrobenzoyl-3-(trifluoroacetamido)-α-L-arabino-hexopyranoside 
• 73864-43-4 cyclohexyl-2,3,6-tridesoxy-4-O-p-nitrobenzoyl-3-(trifluoroacetamido)-β-L-arabino-hexopyranoside 
• 128885-78-9 nitro-4 benzoate de tridesoxy-2,3,6 O-((dihydroxy-5,12 dioxo-6,11 methyl-1 tetrahydro-3,4,6,11 1H-anthra<2,3-c>pyrannyl-3-(1S,3S)) methyl)-1 trifluoroacetamido-3 L-arabino-hexopyrannose 
• 128885-78-9 nitro-4 benzoate de tridesoxy-2,3,6 O-((dihydroxy-5,12 dioxo-6,11 methyl-1 tetrahydro-3,4,6,11 1H-anthra<2,3-c>pyrannyl-3-(1R,3S)) methyl)-1 trifluoroacetamido-3 L-arabino-hexopyrannose 
• 128885-76-7 Nitro-4 benzoate de Tridesoxy-2,3,6 O-((dihydroxy-5,12 dioxo-6,11 tetrahydro-3,4,6,11 1H-anthra<2,3-c>pyrannyl-3(S)) methyl)-1 trifluoroacetamido-3 L-arabino-hexopyrannose 
• 130320-86-4 7-O-(4-O-p-Nitrobenzoyl-2,3,6-trideoxy-3-trifluoroacetylamido-α-L-arabino-hexopyranosyl)-ε-isorhodomycinone 
• 76793-59-4 4-Nitro-benzoic acid (2R,3R,4S,6S)-6-((1S,3S)-3-acetyl-3,5,12-trihydroxy-10-methoxy-6,11-dioxo-1,2,3,4,6,11-hexahydro-naphthacen-1-yloxy)-2-methyl-4-(2,2,2-trifluoro-acetylamino)-tetrahydro-pyran-3-yl ester 
• 70629-87-7 7-O-(2,3,6-tridesoxy-4-O-p-nitrobenzoyl-3-trifluoroacetamido-β-D-arabino-hexopyranosyl)daunomycinone 
• 70629-86-6 7-O-(2,3,6-tridesoxy-4-O-p-nitrobenzoyl-3-trifluoroacetamido-α-D-arabino-hexopyranosyl)daunomycinone 
• 73926-01-9 7-O-<2,3,6-tridesoxy-4-O-p-nitrobenzoyl-3-(trifluoroacetamido)-α-L-arabino-hexopyranosyl>daunomycinone 

Relevant articles and documents

HEMISYNTHESE DE NOUVEAUX GLICOSIDES ANALOGUES DE LA DAUNORUBICINE

Seven daunorubicin analogs containing α-L-, α-D-, and β-D-glicosidic linkages, in which the natural occuring sugar (L-daunosamine) was replaced by diastereomeric 3-amino-2,3,6-trideoxyhexoses (3-epi-L-daunosamine, D-acosamine, D-daunosamine, D-ristosamine, and 3-epi-D-daunosamine), were prepared.In all cases, glycosidation with daunomycinone was performed in the presence of p-toluenesulfonic acid starting from 1-O-acetyl-2,3,6-trideoxy-4-O-p-nitrobenzoyl-3-trifluoro-acetamidohexopyranoses (prepared from the corresponding methyl 3-amino-2,3,6-trideoxyhexopyranosides) or from 1,5-anhydro-2,3,6-trideoxy-4-O-p-nitrobenzoyl-3-trifluoroacetamidohex-1-enitols (prepared from glycosals or pseudoglycals, the 3-amino group being introduced by substitution with sodium azide and subsequent reduction).Glycosidation was followed by removal of the protecting groups.