74043-09-7

Basic information

• Product Name: 4-acetyl-1-trimethylsilylmethyl-1-cyclohexene
• Synonyms: 4-acetyl-1-trimethylsilylmethyl-1-cyclohexene
• CAS NO: 74043-09-7
• Molecular Weight: 210.392
• Mol File: 74043-09-7.mol
• Article Data: 4

Chemical Properties

• CAS DataBase Reference: 4-acetyl-1-trimethylsilylmethyl-1-cyclohexene(CAS DataBase Reference)
• NIST Chemistry Reference: 4-acetyl-1-trimethylsilylmethyl-1-cyclohexene(74043-09-7)
• EPA Substance Registry System: 4-acetyl-1-trimethylsilylmethyl-1-cyclohexene(74043-09-7)

Safety Data

• Hazardous Substances Data: 74043-09-7(Hazardous Substances Data)

Upstream product

• 71092-51-8 (2-methylene-3-butenyl)-trimethyltin 
• 78-94-4 methyl vinyl ketone 
• 70901-64-3 trimethyl(2-methylenebut-3-enyl)silane 

Downstream Products

• 138-86-3 limonene. 
• 499-97-8 pseudolimonene 
• 98-55-5 terpineol 
• 7299-42-5 δ-terpineol 
• 17023-58-4 1-(4-Methylenecyclohexyl)ethanone 
• 6090-09-1 (+-)-4-acetyl-1-methylcyclohexene 
• 82096-14-8 (4-Isopropenyl-cyclohex-1-enylmethyl)-trimethyl-silane 

Relevant articles and documents

Fluorination process

Compounds of formula (II), (IIIa) or (IIIb) (variables are described in the specification) are prepared by fluorination of β,γ-unsaturated alkyl silanes. These compounds are useful as building blocks in the pharmaceutical industry.

HIGHLY REGIOSELECTIVE DIELS-ALDER REACTIONS OF 2-TRIMETHYLSILYLMETHYL-1,3-BUTADIENE CATALYZED BY A LEWIS ACID AND APPLICATIONS TO SYNTHESES OF TERPENES

2-Trimethylsilylmethyl-1,3-butadiene undergoes highly regioselective Diels-Alder reactions with dienophiles such as acrolein and methyl vinyl ketone catalyzed by aluminium chloride in which the "para" isomers are obtained almost exclusively.The adducts are converted readily to a variety of naturally occurring mono and sesquiterpenes.