74043-13-3

Basic information

• Product Name: 5-acetyl-1-trimethylsilylmethyl-1-cyclohexene
• Synonyms: 5-acetyl-1-trimethylsilylmethyl-1-cyclohexene
• CAS NO: 74043-13-3
• Molecular Weight: 210.392
• Mol File: 74043-13-3.mol
• Article Data: 3

Chemical Properties

• CAS DataBase Reference: 5-acetyl-1-trimethylsilylmethyl-1-cyclohexene(CAS DataBase Reference)
• NIST Chemistry Reference: 5-acetyl-1-trimethylsilylmethyl-1-cyclohexene(74043-13-3)
• EPA Substance Registry System: 5-acetyl-1-trimethylsilylmethyl-1-cyclohexene(74043-13-3)

Safety Data

• Hazardous Substances Data: 74043-13-3(Hazardous Substances Data)

Upstream product

• 70901-64-3 trimethyl(2-methylenebut-3-enyl)silane 
• 78-94-4 methyl vinyl ketone 

Relevant articles and documents

Fluorination process

Compounds of formula (II), (IIIa) or (IIIb) (variables are described in the specification) are prepared by fluorination of β,γ-unsaturated alkyl silanes. These compounds are useful as building blocks in the pharmaceutical industry.

HIGHLY REGIOSELECTIVE DIELS-ALDER REACTIONS OF 2-TRIMETHYLSILYLMETHYL-1,3-BUTADIENE CATALYZED BY A LEWIS ACID AND APPLICATIONS TO SYNTHESES OF TERPENES

2-Trimethylsilylmethyl-1,3-butadiene undergoes highly regioselective Diels-Alder reactions with dienophiles such as acrolein and methyl vinyl ketone catalyzed by aluminium chloride in which the "para" isomers are obtained almost exclusively.The adducts are converted readily to a variety of naturally occurring mono and sesquiterpenes.