7436-01-3

Basic information

• Product Name: (1S)-trans-1,2-bis-(toluene-4-sulfonyloxymethyl)-cyclohexane
• Synonyms: (1S)-trans-1,2-bis-(toluene-4-sulfonyloxymethyl)-cyclohexane
• CAS NO: 7436-01-3
• Molecular Weight: 452.593
• Mol File: 7436-01-3.mol
• Article Data: 5

Chemical Properties

• CAS DataBase Reference: (1S)-trans-1,2-bis-(toluene-4-sulfonyloxymethyl)-cyclohexane(CAS DataBase Reference)
• NIST Chemistry Reference: (1S)-trans-1,2-bis-(toluene-4-sulfonyloxymethyl)-cyclohexane(7436-01-3)
• EPA Substance Registry System: (1S)-trans-1,2-bis-(toluene-4-sulfonyloxymethyl)-cyclohexane(7436-01-3)

Safety Data

• Hazardous Substances Data: 7436-01-3(Hazardous Substances Data)

Upstream product

• 610-10-6 (1S,2S)-cyclohexane-1,2-dicarboxylic acid 
• 14166-21-3 (+/-)-trans-1,2-cyclohexanedicarboxylic anhydride 
• 2305-32-0 trans-1,2-cyclohexanedicarboxylic acid 
• 4841-85-4 trans-1,2-bis(ethoxycarbonyl)-4-cyclohexene 
• 96836-97-4 diethyl cyclohexane-trans-1,2-dicarboxylate 
• 76155-27-6 (+/-)-trans-2-(hydroxymethyl)cyclohexylmethanol 
• 98-59-9 p-toluenesulfonyl chloride 
• 65376-05-8 (+)-(1R,2R)-trans-1,2-bis(hydroxymethyl)cyclohexane 
• 3205-34-3 (1S,2S)-(–)-1,2-di(hydroxymethyl)cyclohexane 

Downstream Products

• 190144-08-2 (1S,2S)-1,2-Bis-iodomethyl-cyclohexane 
• 7493-02-9 trans-2-thiahydrindane 
• 85807-79-0 trans-1,2-bis(iodomethyl)cyclohexane 
• 72401-49-1 trans-1,2-bis(mercaptomethyl)cyclohexane 
• 173827-86-6 (1R,2R)-cyclohexane-1,2-diacetonitrile 
• 38261-85-7 (1S,2S)-1,2-bis(bromomethyl)cyclohexane 
• 3205-37-6 (±)-2,2'-((1S,2S)-cyclohexan-1,2-diyl)diacetonitrile 
• 40599-78-8 trans-cyclohexane-1,2-diacetic acid 

Relevant articles and documents

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Deazetation of a Bicyclic Azo Compound: Resolution of a Stereochemical Ambiguity and Conformational Analysis of a Biradical

Development of a new approach has permitted a fuller analysis of the stereochemistry of deazetation of the stereospecifically deuteriated azo compound (1d) than could be achieved previously, in that it has proved possible to analyse 2H2>octa-1,7-diene for E,E-, E,Z,-and Z,Z-content.This has given results for the thermal and photochemical reactions that can be rationalised in terms of partial conformational equilibration of the biradical.

Struktur eines O,N-Ketenacetals: (1RS,8SR,10SR)4(15)Z)-4-Aethyliden-5-oxa-3-azatricyclo3,8>tetradecan)

Methods for the preparation of a series of model compounds which were required for stereochemical studies are described: the tricyclic O,N-ketenacetal 1, the two diastereomeric bicyclic amino acids 7 and 10 (see Scheme 2), and the two diastereomeric conformationally fixed tetrahydro-1,3-oxazines (=1,3-oxazines) 9 and 11.An x-ray analysis of racemic 1 reveals a quasi-tetrahedral nitrogen pyramid of the O,N-ketene acetal grouping, and an almost perfect conformational analogy between the N- and C-centered allylic positions at the double bond.