74592-04-4

Basic information

• Product Name: 1H-Isoindole-1,3(2H)-dione, 2-[(3E)-4-phenyl-3-butenyl]-
• CAS NO: 74592-04-4
• Molecular Formula: C18H15NO2
• Molecular Weight: 277.323
• Mol File: 74592-04-4.mol
• Article Data: 7

Chemical Properties

• CAS DataBase Reference: 1H-Isoindole-1,3(2H)-dione, 2-[(3E)-4-phenyl-3-butenyl]-(CAS DataBase Reference)
• NIST Chemistry Reference: 1H-Isoindole-1,3(2H)-dione, 2-[(3E)-4-phenyl-3-butenyl]-(74592-04-4)
• EPA Substance Registry System: 1H-Isoindole-1,3(2H)-dione, 2-[(3E)-4-phenyl-3-butenyl]-(74592-04-4)

Safety Data

• Hazardous Substances Data: 74592-04-4(Hazardous Substances Data)

Upstream product

• 1074-82-4 potassium phtalimide 
• 591-50-4 iodobenzene 
• 52898-32-5 N-(3-butenyl)phthalimide 
• 7743-29-5 [3-(1,3-dioxo-1,3-dihydro-isoindol-2-yl)-propyl]-triphenyl-phosphonium bromide 
• 100-52-7 benzaldehyde 
• 7515-41-5 (E)-(4-bromobut-1-en-1-yl)benzene 
• 5428-09-1 3-phthalimido-1-propene 
• 25316-59-0 benzyl tri-n-butylammonium bromide 
• 100-44-7 benzyl chloride 

Downstream Products

• 189098-54-2 2-[2-(2-Phenyl-cyclopropyl)-ethyl]-isoindole-1,3-dione 
• 24517-59-7 2-phenyl-1-(4-methylbenzenesulfonyl)pyrrolidine 
• 39551-07-0 (E)-4-methyl-N-(4-phenylbut-3-en-1-yl)benzenesulfonamide 
• 106814-09-9 N-(E)-(4-phenylbut-3-en-1-yl)acetamide 
• 7515-38-0 (E)-4-phenylbut-3-en-1-amine 
• 54981-87-2 2-(4-phenylbutyl)-1H-isoindole-1,3(2H)-dione 

Relevant articles and documents

Vinylation of alkyl halides catalyzed by palladium catalyst

The palladium catalyzed vinylation of alkyl halides, especially benzyl chlorides, with a variety of olefins has been studied. A possible free radical mechanism was proposed.

Alkene Oxyamination Using Malonoyl Peroxides: Preparation of Pyrrolidines and Isoxazolidines

Treatment of homoallylic N-tosyl amines or allylic N-tosyl hydroxylamines with 1.5 equiv of a malonoyl peroxide provides a stereoselective method to access functionalized pyrrolidines and isoxazolidines. This metal free alkene oxyamination proceeds in 50-

Convenient route to primary (Z)-allyl amines and homologs

A convenient two-step procedure for the synthesis of primary (Z)-allyl amines, (Z)-homoallyl amines [(Z)-but-3-enylamines], and (Z)-pent-4-enylamines using the Wittig reaction was achieved. The use of nonstabilized ylides from triphenylphosphonium salt, potassium salt, and apolar solvent produced (Z/E)-geometric isomer ratios generally greater than 1.6. The amine moiety was masked using a phtalimide group that was removed successfully in the last step of the process in two different conditions, NH2NH2/EtOH/rt or CH3NH2/EtOH/rt. However, in some cases, reduction of the C = C double bond in the deprotection with hydrazine was concomitantly observed. Copyright Taylor & Francis Group, LLC.