74972-56-8

Basic information

• Product Name: 6-phenoxyhex-1-ene
• Synonyms: 6-phenoxyhex-1-ene
• CAS NO: 74972-56-8
• Molecular Formula: C₁₂H₁₆O
• Molecular Weight: 176.25
• Mol File: 74972-56-8.mol
• Article Data: 9

Chemical Properties

• Boiling Point: 264.9°C at 760 mmHg
• Flash Point: 100.8°C
• Appearance: /
• Density: 0.922g/cm³
• Vapor Pressure: 0.0155mmHg at 25°C
• Refractive Index: 1.496
• CAS DataBase Reference: 6-phenoxyhex-1-ene(CAS DataBase Reference)
• NIST Chemistry Reference: 6-phenoxyhex-1-ene(74972-56-8)
• EPA Substance Registry System: 6-phenoxyhex-1-ene(74972-56-8)

Safety Data

• Hazardous Substances Data: 74972-56-8(Hazardous Substances Data)

Usage

InChI:InChI=1/C12H16O/c1-2-3-4-8-11-13-12-9-6-5-7-10-12/h2,5-7,9-10H,1,3-4,8,11H2

Upstream product

• 2695-47-8 6-Bromo-1-hexene 
• 108-95-2 phenol 
• 24850-33-7 allyltributylstanane 
• 588-63-6 3-phenoxypropyl bromide 
• 60-29-7 diethyl ether 
• 51795-97-2 6-bromohexyloxybenzene 
• 920-39-8 isopropylmagnesium bromide 
• 884864-24-8 2-(hex-5-enyloxy)iodobenzene 
• 72824-04-5 2-Allyl-4,4,5,5-tetramethyl-1,3,2-dioxaborolane 

Downstream Products

• 64-18-6 formic acid 
• 7170-40-3 5-phenoxyvaleric acid 
• 87841-94-9 5-Phenoxypentanal 
• 861571-88-2 (5-iodo-hexyl)-phenyl ether 
• 1132-66-7 1-phenoxyhexane 
• 19790-63-7 6-phenoxy-1-hexanal 
• 85234-59-9 6-phenoxy-hex-1-ene oxide 
• 93555-05-6 6-phenoxy-hex-1-en-3-one 
• 85234-57-7 6-phenoxy-hex-1-en-3-ol 
• 127298-92-4 C₂₄H₃₄O₂Te 
• 127298-93-5 C₂₄H₃₄O₂Te 
• 127298-97-9 C₂₄H₃₄O₂Te₂ 
• 592-42-7 1,5-Hexadien 
• 693-89-0 1-methylcyclopent-1-ene 

Relevant articles and documents

CYTISINE-LINKED ISOFLAVONOID ANTINEOPLASTIC AGENTS FOR THE TREATMENT OF CANCER

Cytisine-linked isoflavonoids, or pharmaceutically acceptable salts thereof or pharmaceutically acceptable compositions thereof, are useful for the treatment of conditions in which cells have a reliance on peroxisomal HSD17B4 to degrade very long chain fatty acids and provide necessary energy for cell proliferation, such as is seen in colorectal cancer and prostate cancer, for example.

Regioselective Alkoxycarbonylation of Allyl Phenyl Ethers Catalyzed by Pd/dppb under Syngas Conditions

A simple and regioselective synthesis of phenoxy esters and phenylthio esters is reported. The products are obtained by selective alkoxycarbonylation catalyzed by Pd2(dba)3, 1,4-bis(diphenylphisphino)butane (dppb), and syngas (CO/H2) in chloroform/alcohol. This methodology affords bifunctional products in good yield with excellent n-selectivity and without the need to use additives.

Engaging unactivated alkyl, alkenyl and aryl iodides in visible-light-mediated free radical reactions

Radical reactions are a powerful class of chemical transformations. However, the formation of radical species to initiate these reactions has often required the use of stoichiometric amounts of toxic reagents, such as tributyltin hydride. Recently, the use of visible-light-mediated photoredox catalysis to generate radical species has become popular, but the scope of these radical precursors has been limited. Here, we describe the identification of reaction conditions under which photocatalysts such as fac-Ir(ppy) 3 can be utilized to form radicals from unactivated alkyl, alkenyl and aryl iodides. The generated radicals undergo reduction via hydrogen atom abstraction or reductive cyclization. The reaction protocol utilizes only inexpensive reagents, occurs under mild reaction conditions, and shows exceptional functional group tolerance. Reaction efficiency is maintained upon scale-up and decreased catalyst loading, and the reaction time can be significantly shortened when the reaction is performed in a flow reactor.