7499-59-4

Basic information

• Product Name: chrysen-6-yl acetate
• CAS NO: 7499-59-4
• Molecular Formula: C₂₀H₁₄O₂
• Molecular Weight: 286.324
• Mol File: 7499-59-4.mol
• Article Data: 2

Chemical Properties

• Boiling Point: 500.7°C at 760 mmHg
• Flash Point: 153.8°C
• Density: 1.248g/cm³
• Vapor Pressure: 3.7E-10mmHg at 25°C
• Refractive Index: 1.725
• CAS DataBase Reference: chrysen-6-yl acetate(CAS DataBase Reference)
• NIST Chemistry Reference: chrysen-6-yl acetate(7499-59-4)
• EPA Substance Registry System: chrysen-6-yl acetate(7499-59-4)

Safety Data

• Hazardous Substances Data: 7499-59-4(Hazardous Substances Data)

Upstream product

• 37515-51-8 6-hydroxychrysene 
• 857619-20-6 2-diazo-1-(2-[2]naphthyl-phenyl)-ethanone 
• 855754-28-8 acetic acid-(11,12-dihydro-chrysen-6-yl ester) 
• 62018-15-9 2-(2-phenylnaphthalen-1-yl)acetic acid 
• 108-24-7 acetic anhydride 
• 64-19-7 acetic acid 
• 5435-44-9 (E)-3-Ureido-but-2-enoic acid ethyl ester 
• 7664-93-9 sulfuric acid 
• 7496-02-8 6-nitrochrysene 
• 15131-84-7 chrysene 5,6-oxide 
• 218-01-9 chrysene 
• 2642-98-0 6-aminochrysene 

Downstream Products

• 37515-51-8 6-hydroxychrysene 

Relevant articles and documents

Chemical Oxidation of Nitrated Polycyclic Aromatic Hydrocarbons: Hydroxylation with Superoxide Anion Radical

Nitrated polycyclic aromatic hydrocarbon (nitroPAH) is a potent mutagen which is reductively and/or oxidatively metabolized. Biological oxidation of nitroPAH, such as hydroxylation and epoxidation, is known, but chemical oxidation has been reported in only a few papers. NitroPAH is barely oxidized by various chemical oxidants because of the electron deficient property of the aromatic ring with the nitro substituent. Nucleophilic reactivity of superoxide anion radical is known, and thus the oxidation of nitroPAH with the chemically generated superoxide anion radical was carried out in this study. When 1-nitropyrene was reacted with KO2/18-crown-6 in dimethylformamide, 5-, 6-, 8-, and 9-hydroxy-1-nitropyrenes and 1-hydroxypyrene were obtained in preparative yields. Three isomeric dinitropyrenes, 3-nitrofluoranthene, 6-nitrobenzopyrene, and 6-nitrochrysene, were oxidized to hydroxy derivatives, some of which correspond to the oxidative metabolite of nitroPAH. The oxidation of dinitropyrenes with trifluoroperacetic acid gave K-region oxidized products.