75010-39-8

Basic information

• Product Name: 1-(3,4-dimethoxyphenyl)-2-(p-toluenesulfonyloxy)ethane
• Synonyms: 1-(3,4-dimethoxyphenyl)-2-(p-toluenesulfonyloxy)ethane
• CAS NO: 75010-39-8
• Molecular Weight: 336.409
• Mol File: 75010-39-8.mol
• Article Data: 8

Chemical Properties

• CAS DataBase Reference: 1-(3,4-dimethoxyphenyl)-2-(p-toluenesulfonyloxy)ethane(CAS DataBase Reference)
• NIST Chemistry Reference: 1-(3,4-dimethoxyphenyl)-2-(p-toluenesulfonyloxy)ethane(75010-39-8)
• EPA Substance Registry System: 1-(3,4-dimethoxyphenyl)-2-(p-toluenesulfonyloxy)ethane(75010-39-8)

Safety Data

• Hazardous Substances Data: 75010-39-8(Hazardous Substances Data)

Upstream product

• 120-14-9 3,4-dimethoxy-benzaldehyde 
• 121-33-5 vanillin 
• 7786-61-0 3-methoxy-4-hydroxystyrene 
• 6380-23-0 3,4-dimethoxystyrene 
• 81316-62-3 ethyl 2-(3,4-dimethoxyphenyl)acetoimidate hydrochloride 
• 18066-68-7 ethyl 3,4-dimethoxyphenylacetate 
• 98-59-9 p-toluenesulfonyl chloride 
• 7417-21-2 2-(3,4-dimethoxyphenyl)ethyl alcohol 

Downstream Products

• 64728-23-0 2-(3,4-dimethoxyphenyl)-1-iodoethane 
• 74996-67-1 1,3-bis<2-(3,4-dimethoxy-phenylethyl)>imidazolidin-2-one 
• 74996-66-0 1-<2-(3,4-dimethoxyphenyl)ethyl>imidazolidin-2-one 
• 85709-84-8 1-(3,4-dimethoxyphenyl)-2-(methylseleno)ethane 
• 6380-23-0 3,4-dimethoxystyrene 
• 56014-51-8 1-[2-(3,4-dimethoxyphenyl)ethyl]-1H-pyrrole 
• 864528-55-2 4-(2-azidoethyl)-1,2-dimethoxybenzene 
• 1335128-21-6 4-((4-chlorophenyl)(hydroxyl)methyl)-1-(3,4-dimethoxyphenethyl)-1H-1,2,3-triazole 
• 1443128-10-6 C₃₁H₃₆O₈ 
• 1443128-45-7 C₃₁H₃₈O₇ 

Relevant articles and documents

Attempts to mimic key bond-forming events associated with the proposed biogenesis of the pentacyclic lamellarins

The pyrrole-tethered veratroles 16 and 27 each engage in PIFA-induced oxidative cyclization reactions to give compounds 22 and 29, respectively, which incorporate a key tricyclic fragment associated with the title natural products. In contrast, the corresponding catechols 11 and 12 only produce polymeric materials on subjection to analogous reaction conditions. Efforts to study lactone ring formation by the oxidative cyclization of catechol 30 and veratrole 38 have been thwarted by an inability to prepare the former substrate and decomposition of the latter. The reported conversions 44 ? 45 and 46 ? 47 suggest that a C2-carboxy group attached to the pyrrole ring can ?direct' the oxidative cyclization of N-tethered aryl groups. The acquisition of compound 22 by the means described herein provides an adventitious and concise route to the racemic modification of the pyrrolo[2,1-a]isoquinoline alkaloid crispine A (52). CSIRO 2008.

One-pot cascade synthesis of azabicycles via the nitro-Mannich reaction and N -alkylation

A one-pot, metal-free process for the synthesis of azabicycles is developed. The key transformations involved a cascade of double intramolecular cyclizations via the nitro-Mannich reaction and N-alkylation, providing various ring systems of azabicycles in

Synthesis and biological evaluation of isosteric analogs of mandipropamid for the control of oomycete pathogens

A series of isosteric analogs of mandipropamid were designed and synthesized via 'click chemistry'. The amide bond of mandipropamid was substituted by a 1,2,3-triazole functional group. The bioassay results have indicated that some of the title compounds exhibited moderate fungicidal activity against Pseudoperonospora cubensis, and the activity has been systematically studied as a function of molecular structure. The low activity of the mandipropamid analog that contains a lipid chain is likely due to the presence of a weak hydrogen bond donor in the 1,2,3-triazole. Furthermore, we have performed the molecular modeling and found that N-methylamide could be more effective than amide as the surrogates to 1,2,3-triazole, which ultimately leads to a longer distance (1.1A longer) between the two substitutes in the 1,4-disubstituted 1,2,3-triazole compound.