763-29-1Relevant articles and documents
ETUDE DE LA DIMERISATION DU PROPYLENE CATALYSEE EN PHASE HOMOGENE PAR DES ESPECES DU TYPE "HCoLx"
Petit, F.,Masotti, H.,Peiffer, G.,Buono, G.
, p. 273 - 282 (1983)
The dimerisation of propylene in methylpentenes (60percent) at 25 deg C is catalysed by two active cobalt species.The first, HCoL3, issued from the system "Co(Acac)3/HAlEt2/L" in the presence of 1,5-cyclooctadiene, is more active (*30) and selective in 2-methyl-1-pentene (85percent of dimers) than the second, formed from HCo(COD)2.Under low pressures of propylene (3 bar), the fraction of higher oligomers (mainly trimers) increases only up to 40percent.
Nickel Hydride Complexes Supported by a Pyrrole-Derived Phosphine Ligand
Collett, Joel D.,Guan, Hairong,Krause, Jeanette A.
, p. 345 - 353 (2022/02/16)
The synthesis of two nickel hydride complexes bearing the pyrrole-derived phosphine ligand CyPNH (2-(dicyclohexylphosphino)methyl-1H-pyrrole) was developed, namely, (κP-CyPNH)(κP,κN-CyPN)NiH and the acid-stable trans-(κP-CyPNH)2Ni(OAc)H·HOAc. (κP-CyPNH)(κP,κN-CyPN)NiH stoichiometrically reduces benzaldehyde and acetophenone in a metal-ligand cooperative manner and catalytically dimerizes ethylene and cycloisomerizes 1,5-cyclooctadiene and 1,5-hexadiene. trans-(κP-CyPNH)2Ni(OAc)H·HOAc, available from the protonation of (κP-CyPNH)(κP,κN-CyPN)NiH with acetic acid, catalyzes the cycloisomerization of 1,5-cyclooctadiene more effectively and produces the less thermodynamically favored cycloisomers of 1,5-cyclooctadiene.
METAL ORGANIC FRAMEWORKS, THEIR SYNTHESIS AND USE
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Page/Page column 15, (2018/11/26)
A novel metal organic framework, EMM-33, is described having the structure of UiO-67 and comprising bisphosphonate linking ligands. EMM-33 has acid activity and is useful as a catalyst in olefin isomerization. Also disclosed is a process of making metal organic frameworks, such as EMM-33, by heterogeneous ligand exchange, in which linking ligands having a first bonding functionality in a host metal organic framework are exchanged with linking ligands having a second different bonding functionality in the framework.
Dimerization method for high activity and selectivity propylene
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Paragraph 0114; 0115; 0116; 0118-0121; 0124-0139; 0142-0153, (2017/06/02)
The invention provides a dimerization method for high activity and selectivity propylene. The method includes the following steps that methylaluminoxane (MAO) or modified methylaluminoxane (MMAO) is used as a catalyst promoter, and the propylene is subjected to a dimerization reaction under the catalytic action of an ethylidene bridged substituted diindene titanium group metal complex catalyst; and the ethylidene bridged substituted diindene titanium group metal complex catalyst is an internal compensation (meso-) ethylidene bridged substituted diindene titanium group metal complex catalyst or a racemization (rac-) ethylidene bridged substituted diindene titanium group metal complex catalyst. Compared with the prior art, the dimerization method provided by the invention is high in catalytic activity and high in dimerization selectivity, the rate can reach 99%, numerous follow-up operation steps in separation of products with the high degree of polymerization are omitted, the industrialization cost is reduced, and the industrial production needs can be met.