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7699-41-4

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7699-41-4 Usage

Description

Silicic acid, also known as silicic acid salts or orthosilicic acid, is a group of chemical compounds composed of hydrogen, silicon, and oxygen with the formula [SiOx(OH)4-2x]n, where H4SiO4 is the most predominant form. It is a hydrated form of silicon dioxide and belongs to the family of Miscellaneous Silicates, which are inorganic compounds with silicate as the largest metallic oxoanion. Silicic acid is found in various foods, such as grains, fruits, and vegetables, and has a wide range of applications in different industries.

Uses

1. Laboratory Reagent and Reinforcing Agent in Rubber:
Silicic acid is used as a laboratory reagent and reinforcing agent in the rubber industry. It enhances the strength and durability of rubber products, making them more resistant to wear and tear.
2. Protein Chromatography:
In the field of biochemistry, silicic acid is used in protein chromatography, a technique used to separate and purify proteins based on their size, shape, and charge.
3. Anti-biofilm Potential:
Silicic acid has been utilized in a study to demonstrate the anti-biofilm potential of a glycolipid surfactant produced by a tropical marine strain of Serratia marcescens. This application highlights its use in the field of microbiology and biotechnology.
4. Antioxidant Activity Studies:
Silicic acid has been used to study the antioxidant activity of fresh and processed Jalapeno and Serrano peppers, contributing to the field of food science and nutrition.
5. Toothpaste Manufacturing:
Silicic acid is commonly used in the manufacture of toothpastes, where it acts as an abrasive agent to help remove plaque and stains from teeth.
6. Chromatography Stationary Phase:
It is used as a stationary phase for chromatography, a technique used to separate mixtures of substances into their individual components.
7. Catalyst and Catalyst Carrier Manufacturing:
Silicic acid is utilized in the manufacture of catalysts and catalyst carriers, which are essential in various chemical reactions and industrial processes.
8. Tungsten Filament Production:
It is involved in the production of tungsten filaments as a chemical reagent and flux, playing a crucial role in the manufacturing of light bulbs and other electrical components.
9. Oil and Wax Decolorizing:
Silicic acid is used for oil and wax decolorizing, where it helps in removing impurities and improving the appearance and quality of the final product.

Biochem/physiol Actions

Silicic acid polymers are employed in water treatment systems, drug encapsulation cum delivery and for soluble nanoparticle generation. Silicic acid interacts with aluminum and reduces its bioavailability. It is an effective antidote for aluminum poisoning.

Safety Profile

An inhalation hazard. Poison by intravenous route. An eye irritant and nuisance dust. Questionable carcinogen. Mutation data reported. See also other silica entries and SILICATES

Check Digit Verification of cas no

The CAS Registry Mumber 7699-41-4 includes 7 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 4 digits, 7,6,9 and 9 respectively; the second part has 2 digits, 4 and 1 respectively.
Calculate Digit Verification of CAS Registry Number 7699-41:
(6*7)+(5*6)+(4*9)+(3*9)+(2*4)+(1*1)=144
144 % 10 = 4
So 7699-41-4 is a valid CAS Registry Number.
InChI:InChI=1/H2O3Si.H2O/c1-4(2)3;/h1-2H;1H2

7699-41-4 Well-known Company Product Price

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  • Sigma

  • (SILA200)  Silicicacid  suitable for column chromatography, 60-200 mesh

  • 7699-41-4

  • SILA200-100G

  • 1,402.83CNY

  • Detail
  • Sigma

  • (SILA200)  Silicicacid  suitable for column chromatography, 60-200 mesh

  • 7699-41-4

  • SILA200-500G

  • 4,744.35CNY

  • Detail

7699-41-4SDS

SAFETY DATA SHEETS

According to Globally Harmonized System of Classification and Labelling of Chemicals (GHS) - Sixth revised edition

Version: 1.0

Creation Date: Aug 16, 2017

Revision Date: Aug 16, 2017

1.Identification

1.1 GHS Product identifier

Product name metasilicic acid

1.2 Other means of identification

Product number -
Other names SILICIC ACID

1.3 Recommended use of the chemical and restrictions on use

Identified uses For industry use only.
Uses advised against no data available

1.4 Supplier's details

1.5 Emergency phone number

Emergency phone number -
Service hours Monday to Friday, 9am-5pm (Standard time zone: UTC/GMT +8 hours).

More Details:7699-41-4 SDS

7699-41-4Synthetic route

sodium silicate

sodium silicate

sulfuric acid
7664-93-9

sulfuric acid

silicic acid
7699-41-4

silicic acid

Conditions
ConditionsYield
In water
sodium metasilicate nonahydrate

sodium metasilicate nonahydrate

nitric acid
7697-37-2

nitric acid

silicic acid
7699-41-4

silicic acid

Conditions
ConditionsYield
In water at 40℃; for 1h; pH=5;
hydrogenchloride
7647-01-0

hydrogenchloride

sodium silicate

sodium silicate

silicic acid
7699-41-4

silicic acid

Conditions
ConditionsYield
In water at 20℃; for 24h;
diethyl isopropylidenemalonate
6802-75-1

diethyl isopropylidenemalonate

1,14-dibromotetradecane
37688-96-3

1,14-dibromotetradecane

silicic acid
7699-41-4

silicic acid

tetraethyl 3,3,18,18-tetramethyleicosanetetraoate
103199-02-6

tetraethyl 3,3,18,18-tetramethyleicosanetetraoate

Conditions
ConditionsYield
copper(l) chloride In tetrahydrofuran; petrol ether; benzene86%
Ethyl 3-bromopropionate
539-74-2

Ethyl 3-bromopropionate

2-amino-3,5-dimethoxyacetophenone
23042-76-4

2-amino-3,5-dimethoxyacetophenone

silicic acid
7699-41-4

silicic acid

2'-(N-2-Carbethoxyethylamino)-3',5'-dimethoxyacetophenone
98300-29-9

2'-(N-2-Carbethoxyethylamino)-3',5'-dimethoxyacetophenone

Conditions
ConditionsYield
With sodium acetate; acetic acid In dichloromethane; water; ethyl acetate66.3%
With sodium acetate; acetic acid In chloroform-d1; dichloromethane; water; ethyl acetate
alumina hydrate

alumina hydrate

silicic acid
7699-41-4

silicic acid

Modified catalyst support EXAMPLE S3

Modified catalyst support EXAMPLE S3

Conditions
ConditionsYield
Stage #1: alumina hydrate; silicic acid In water at 100℃; for 16h;
Stage #2: at 725℃; for 4h;
silicic acid
7699-41-4

silicic acid

1-[3-({[tert-butyl(diphenyl)silyl]oxy}methyl)-2,4-dichlorophenyl]-1H-pyrrole-2-carbonitrile
189268-26-6

1-[3-({[tert-butyl(diphenyl)silyl]oxy}methyl)-2,4-dichlorophenyl]-1H-pyrrole-2-carbonitrile

1-(3-tert-butyldiphenylsilyloxymethyl-2,4-dichlorophenyl)-4-chloro-2-cyanopyrrole

1-(3-tert-butyldiphenylsilyloxymethyl-2,4-dichlorophenyl)-4-chloro-2-cyanopyrrole

Conditions
ConditionsYield
With tert-butylhypochlorite In tetrachloromethane
With tert-butylhypochlorite In tetrachloromethane
methyl cis-2-[(1-(4-Bromobenzyl)-5-methoxy-2-methyl-1H-indol-3-yl)methyl]cyclopropanecarboxylate

methyl cis-2-[(1-(4-Bromobenzyl)-5-methoxy-2-methyl-1H-indol-3-yl)methyl]cyclopropanecarboxylate

silicic acid
7699-41-4

silicic acid

trans-2-[(1-(4-Bromobenzyl)-5-methoxy-2-methyl-1H-indol-3-yl)methyl]cyclopropanecarboxylic acid

trans-2-[(1-(4-Bromobenzyl)-5-methoxy-2-methyl-1H-indol-3-yl)methyl]cyclopropanecarboxylic acid

Conditions
ConditionsYield
With sodium hydroxide; citric acid In tetrahydrofuran; methanol; hexane; ethyl acetate
5,12-epoxy-1,2,3,4,5,12-hexahydro-2-naphtacenyl methyl ketone
73862-81-4

5,12-epoxy-1,2,3,4,5,12-hexahydro-2-naphtacenyl methyl ketone

silicic acid
7699-41-4

silicic acid

2-acetyl-1,2,3,4-tetrahydro-5,12-naphtacenequinone
76811-54-6

2-acetyl-1,2,3,4-tetrahydro-5,12-naphtacenequinone

Conditions
ConditionsYield
With trifluoroacetic acid In diethyl ether; dichloromethane; chloroform
1-methoxy-6,6-dimethyl-6H-benzo[c]chromen-3-ol
55815-69-5

1-methoxy-6,6-dimethyl-6H-benzo[c]chromen-3-ol

1-(3-hydroxy-1-methoxy-6,6-dimethyl-6H-benzo[c]chromen-4-yl)-ethanone
55815-58-2

1-(3-hydroxy-1-methoxy-6,6-dimethyl-6H-benzo[c]chromen-4-yl)-ethanone

oxalic acid diethyl ester
95-92-1

oxalic acid diethyl ester

silicic acid
7699-41-4

silicic acid

ethanolamine salt of 2-carboxy-4-oxo-6,6-dimethyl-11-methoxy-4H,6H-[2]-benzopyrano-[3,4-f]-[1]-benzopyran
57394-20-4

ethanolamine salt of 2-carboxy-4-oxo-6,6-dimethyl-11-methoxy-4H,6H-[2]-benzopyrano-[3,4-f]-[1]-benzopyran

Conditions
ConditionsYield
With hydrogenchloride; sodium hydroxide; sodium; acetic acid In ethanol; water; benzene
(1,1-dimethyl-butyl)-urea
15363-96-9

(1,1-dimethyl-butyl)-urea

methyl 4-bromo-3-oxobutanoate
17790-81-7

methyl 4-bromo-3-oxobutanoate

silicic acid
7699-41-4

silicic acid

1-(1,1-dimethylbutyl)-3-(2,5-dihydro-5-oxo-furan-3-yl)urea

1-(1,1-dimethylbutyl)-3-(2,5-dihydro-5-oxo-furan-3-yl)urea

Conditions
ConditionsYield
With toluene-4-sulfonic acid In methanol; ethyl acetate; benzene
With toluene-4-sulfonic acid In methanol; ethyl acetate; benzene
2,5-dimethylfuran
625-86-5

2,5-dimethylfuran

silicic acid
7699-41-4

silicic acid

A

bis (2,5-dimethyl-furan-3-yl)-disulfide
28588-73-0

bis (2,5-dimethyl-furan-3-yl)-disulfide

B

bis (2,5-dimethyl-furan-3-yl)-sulfide

bis (2,5-dimethyl-furan-3-yl)-sulfide

Conditions
ConditionsYield
With SCl2; sulphur dichloride; tin(IV) chloride In (2S)-N-methyl-1-phenylpropan-2-amine hydrate; diethyl ether; hexane
benzeneethyl acetate-methanol

benzeneethyl acetate-methanol

1,1-dimethylethylurea
1118-12-3

1,1-dimethylethylurea

4-methyl-1,1-dioxo-dihydro-1λ6-thiophen-3-one
39246-95-2

4-methyl-1,1-dioxo-dihydro-1λ6-thiophen-3-one

silicic acid
7699-41-4

silicic acid

1-tert-butyl-3-(4-methyl-4,5-dihydro-3-thienyl)urea S,S-dioxide
58254-33-4

1-tert-butyl-3-(4-methyl-4,5-dihydro-3-thienyl)urea S,S-dioxide

Conditions
ConditionsYield
With toluene-4-sulfonic acid In benzene
dl-2β-formyl-3α-(dimethyl-t-butylsilyl)oxy-5-oxocyclopentane-1α-heptanoic acid
62413-89-2

dl-2β-formyl-3α-(dimethyl-t-butylsilyl)oxy-5-oxocyclopentane-1α-heptanoic acid

silicic acid
7699-41-4

silicic acid

3α-[(dimethyl-t-butylsilyl)oxy]-2β-(8-bromo-3-oxo-1-octenyl)-5-oxocyclopentane-1α-heptanoic acid
62344-09-6

3α-[(dimethyl-t-butylsilyl)oxy]-2β-(8-bromo-3-oxo-1-octenyl)-5-oxocyclopentane-1α-heptanoic acid

Conditions
ConditionsYield
In benzene
In benzene
methylene chloride-water

methylene chloride-water

methylene chloride (9.75 liters)-water

methylene chloride (9.75 liters)-water

2,2'-[(3-aminopropyl)imino]bis-ethanol
4985-85-7

2,2'-[(3-aminopropyl)imino]bis-ethanol

silicic acid
7699-41-4

silicic acid

1-Bromooctadecane
112-89-0

1-Bromooctadecane

N,N-dioctadecyl-N',N'-bis(2-hydroxyethyl)1,3-propanediamine
35607-20-6

N,N-dioctadecyl-N',N'-bis(2-hydroxyethyl)1,3-propanediamine

Conditions
ConditionsYield
With sodium hydroxide; succinic acid; potassium carbonate In dichloromethane; acetone
4(6-carbomethoxyhexyl)-5-(3-keto-1-trans-octenyl)-thiazole
58176-94-6

4(6-carbomethoxyhexyl)-5-(3-keto-1-trans-octenyl)-thiazole

silicic acid
7699-41-4

silicic acid

4-(6-carbomethoxyhexyl)-5-(3-hydroxy-1-trans-octenyl)-thiazole
58176-96-8

4-(6-carbomethoxyhexyl)-5-(3-hydroxy-1-trans-octenyl)-thiazole

Conditions
ConditionsYield
With sodium borohydrid In n-heptane; water; ethyl acetate; isopropyl alcohol
2-(7-hydroxyheptyl)-2-cyclopenten-1-one
33803-57-5

2-(7-hydroxyheptyl)-2-cyclopenten-1-one

silicic acid
7699-41-4

silicic acid

2-(7-chloroheptyl)-2-cyclopentenone
72489-60-2

2-(7-chloroheptyl)-2-cyclopentenone

Conditions
ConditionsYield
With triphenylphosphine In tetrachloromethane; dichloromethane; benzene
sodium dithionite

sodium dithionite

cobalt(II) chloride hexahydrate

cobalt(II) chloride hexahydrate

silicic acid
7699-41-4

silicic acid

sodium hydroxide
1310-73-2

sodium hydroxide

[(Si7.93)(Co5.92)O20(OH)4]Na0.42

[(Si7.93)(Co5.92)O20(OH)4]Na0.42

Conditions
ConditionsYield
In neat (no solvent) mixing, according to: Mizutani T., et al., Clays Clay Miner. 1991, 39, 381, hydrothermal treatment (150°C, 50 h); washing floculent solids (distd. water), stirring (1 M NaCl, overnight),washing (distd. water), dialyzing (Spectra/por 3 membrane);
sodium dithionite

sodium dithionite

cobalt(II) chloride hexahydrate

cobalt(II) chloride hexahydrate

silicic acid
7699-41-4

silicic acid

sodium hydroxide
1310-73-2

sodium hydroxide

[(Si8.05)(Co5.58)O20(OH)4]Na0.66

[(Si8.05)(Co5.58)O20(OH)4]Na0.66

Conditions
ConditionsYield
In neat (no solvent) mixing, according to: Mizutani T., et al., Clays Clay Miner. 1991, 39, 381, hydrothermal treatment (250°C, 15 h, 500 psi of Ar), according to: Bruce, L. A. et al., Clays Clay Miner 1986, 34, 25; washing floculent solids (distd. water), stirring (1 M NaCl, overnight),washing (distd. water), dialyzing (Spectra/por 3 membrane);
lithium nitrate

lithium nitrate

silver nitrate

silver nitrate

ferric nitrate
7782-61-8

ferric nitrate

silicic acid
7699-41-4

silicic acid

100Fe/2Li/1Ag/10SiO2

100Fe/2Li/1Ag/10SiO2

Conditions
ConditionsYield
Stage #1: ferric nitrate With water; ammonium carbonate pH=6;
Stage #2: lithium nitrate; silicic acid In water at 300℃; for 5h;
Stage #3: silver nitrate With hydrogen more than 3 stages;
lithium carbonate
554-13-2

lithium carbonate

silver nitrate

silver nitrate

ferric nitrate
7782-61-8

ferric nitrate

silicic acid
7699-41-4

silicic acid

calcium carbonate

calcium carbonate

100Fe/2Li/1Ag/1.5Ca/25SiO2

100Fe/2Li/1Ag/1.5Ca/25SiO2

Conditions
ConditionsYield
Stage #1: ferric nitrate With water; ammonium carbonate pH=6;
Stage #2: lithium carbonate; calcium carbonate In water
Stage #3: silica gel; silver nitrate; silicic acid With hydrogen more than 3 stages;
lithium carbonate
554-13-2

lithium carbonate

silver nitrate

silver nitrate

ferric nitrate
7782-61-8

ferric nitrate

silicic acid
7699-41-4

silicic acid

100Fe/2Li/1Ag/25SiO2

100Fe/2Li/1Ag/25SiO2

Conditions
ConditionsYield
Stage #1: ferric nitrate With water; ammonium carbonate pH=6;
Stage #2: lithium carbonate In water
Stage #3: silica gel; silver nitrate; silicic acid With hydrogen more than 3 stages;
lithium carbonate
554-13-2

lithium carbonate

potassium hydrogencarbonate
298-14-6

potassium hydrogencarbonate

silver nitrate

silver nitrate

ferric nitrate
7782-61-8

ferric nitrate

silicic acid
7699-41-4

silicic acid

100Fe/0.2K/4Li/1Ag/25SiO2

100Fe/0.2K/4Li/1Ag/25SiO2

Conditions
ConditionsYield
Stage #1: ferric nitrate With water; ammonium carbonate pH=6;
Stage #2: lithium carbonate; potassium hydrogencarbonate In water
Stage #3: silica gel; silver nitrate; silicic acid With hydrogen more than 3 stages;
lithium carbonate
554-13-2

lithium carbonate

silver nitrate

silver nitrate

ferric nitrate
7782-61-8

ferric nitrate

silicic acid
7699-41-4

silicic acid

100Fe/2Li/1Ag/10SiO2

100Fe/2Li/1Ag/10SiO2

Conditions
ConditionsYield
Stage #1: ferric nitrate With water; ammonium carbonate pH=6;
Stage #2: lithium carbonate; silicic acid In water at 300℃; for 5h;
Stage #3: silver nitrate With carbon monoxide more than 3 stages;
lithium carbonate
554-13-2

lithium carbonate

potassium hydrogencarbonate
298-14-6

potassium hydrogencarbonate

silver nitrate

silver nitrate

ferric nitrate
7782-61-8

ferric nitrate

silicic acid
7699-41-4

silicic acid

100Fe/3K/1.2Li/2Ag/25SiO2

100Fe/3K/1.2Li/2Ag/25SiO2

Conditions
ConditionsYield
Stage #1: ferric nitrate With water; ammonium carbonate pH=6;
Stage #2: lithium carbonate; potassium hydrogencarbonate; silicic acid In water at 300℃; for 5h;
Stage #3: silver nitrate With hydrogen more than 3 stages;
lithium hydroxide monohydrate
1310-66-3

lithium hydroxide monohydrate

silicic acid
7699-41-4

silicic acid

lithium metasilicate

lithium metasilicate

Conditions
ConditionsYield
In acetone Milling; Heating;

7699-41-4Relevant articles and documents

AlCl3 immobilized on silicic acid as efficient Lewis acid catalyst for highly selective preparation of dicyclohexylamine from the vapor phase hydroamination of cyclohexene with cyclohexylamine

Ai, Qiuhong,Jian, Jian,Liu, Pingle,Luo, He'an,Wen, Jingbin,You, Kuiyi,Zhao, Fangfang

, (2020/07/21)

An efficient and stable Lewis acid catalyst silicic acid (SA)-immobilized AlCl3 (AlCl3-SA) has been successfully prepared by the chemical bonding method in this work. The results indicated that the immobilized 15percentAlCl3-SA exhibited excellent catalytic performance and stability in the vapor phase hydroamination of cyclohexene with cyclohexylamine. 58.5percent cyclohexene conversion with 98.7percent selectivity to dicyclohexylamine was still maintained after running for over 150 h, and the space time yield of dicyclohexylamine was 142.6 mol/h·m3. The developed AlCl3-SA catalyst had the advantages of low cost and long-time stable activity. Maybe this work provides a promising approach for hydroamination of olefins to amines.

Conversion of benzyl alcohol to benzonitrile over a Cu10.3/SiO2 catalyst

Zhang, Yuecheng,Zhao, Xiaofu,Zhang, Hongyu,Yan, Xiang,Zhao, Jiquan

, p. 45 - 53 (2016/05/09)

A Cu10.3/SiO2 catalyst was prepared for the conversion of benzyl alcohol to benzonitrile through amination-dehydrogenation process. The catalyst showed high activity in the reaction, and a yield as high as 98.0% was reached under the optimized conditions. The catalyst was characterized by XRD, TEM-EDX, TG-DSC, N2 adsorption-desorption and IR of absorbed pyridine methods. The characterization results disclosed that the doping of copper created Lewis acid sites in the matrix of SiO2. The doped copper in the fresh catalyst was present in CuO state, which was reduced to elemental Cu by H2 generated in situ in the catalytic run. The characterization results also disclosed that the catalyst deactivation was mainly caused by the carbonaceous deposition on the surface of the catalyst in the catalytic reaction. The experimental results confirmed that most activity of the catalyst can be recovered at 550°C online by blowing air into the reactor. Partial sintering of copper particles took place during the catalytic run, which led to the slight decreases of Lewis acidity and dehydrogenation capacity, therefore, caused deviation of the performance of the regenerated Cu10.3/SiO2 catalyst from that of the fresh one.

Process for making highly active and selective catalysts for the production of unsaturated nitriles

-

, (2008/06/13)

An improved catalyst for the production of unsaturated nitriles from their corresponding olefins, the catalyst having the atomic ratios described by the empirical formula BiaMobVcSbdNbeAfBgOx and methods of making and using the same.

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