7714-93-4Relevant articles and documents
Aerobic Copper(II)-catalyzed synthesis of β-hydroxysulfides and selenides from alkenes with disulfides and diselenides
Taniguchi, Nobukazu
, (2022/03/07)
A copper-catalyzed hydroxysulfenylation of alkenes was achieved using disulfides in the presence of n-Bu4NI and H2O. The procedure smoothly proceeded under air atmosphere, and the corresponding β-hydroxysulfides were obtained with regio- and anti-selectivity in good yields. Furthermore, a reaction using diselenides effectively produced the expected β-hydroxyselenides. These reactions could use both chalcogenide groups on dichalcogenides. Further the procedure also worked for hydrosulfenylation using thiols.
Metal-Free Chlorothiolation of Alkenes Using HCl and Sulfoxides
Ebule, Rene,Hammond, Gerald B.,Xu, Bo
supporting information, p. 4705 - 4708 (2018/09/06)
We report a novel method for the chlorothiolation of alkenes using HCl and sulfoxides to achieve the 1,2-difunctionalization of unactivated alkenes. The combination of our new HCl reagent (HCl/DMPU) with sulfoxides forms a unique chlorothiolation system.
Ammonium iodide-induced sulfonylation of alkenes with DMSO and water toward the synthesis of vinyl methyl sulfones
Gao, Xiaofang,Pan, Xiaojun,Gao, Jian,Huang, Huawen,Yuan, Gaoqing,Li, Yingwei
supporting information, p. 210 - 212 (2015/01/09)
A novel ammonium iodide-induced sulfonylation of alkenes with DMSO and water toward the synthesis of vinyl methyl sulfones is described. The process proceeded smoothly under metal-free conditions with high stereoselectivity and good functional group toler