77470-68-9

Basic information

• Product Name: 2-Propenal, 3-(4-bromophenyl)-3-(3-pyridinyl)-, (Z)-
• CAS NO: 77470-68-9
• Molecular Formula: C14H10BrNO
• Molecular Weight: 288.143
• Mol File: 77470-68-9.mol
• Article Data: 2

Chemical Properties

• CAS DataBase Reference: 2-Propenal, 3-(4-bromophenyl)-3-(3-pyridinyl)-, (Z)-(CAS DataBase Reference)
• NIST Chemistry Reference: 2-Propenal, 3-(4-bromophenyl)-3-(3-pyridinyl)-, (Z)-(77470-68-9)
• EPA Substance Registry System: 2-Propenal, 3-(4-bromophenyl)-3-(3-pyridinyl)-, (Z)-(77470-68-9)

Safety Data

• Hazardous Substances Data: 77470-68-9(Hazardous Substances Data)

Upstream product

• 70263-43-3 1-(4-Bromophenyl)-1-(3-pyridyl)-2-propen-1-ol 
• 56775-88-3 Zimelidine 
• 77470-73-6 (Z)-3-(4-bromophenyl)-3-(3-pyridinyl)prop-2-en-1-ol 

Downstream Products

• 83049-64-3 (E)-3-(4-Bromophenyl)-3-(3-pyridyl)propenal 
• 77470-73-6 (Z)-3-(4-bromophenyl)-3-(3-pyridinyl)prop-2-en-1-ol 
• 91671-10-2 3-[(Z)-1-(4-Bromo-phenyl)-3-methoxy-propenyl]-pyridine 
• 56775-88-3 Zimelidine 
• 56775-89-4 (E)-3-(4-bromophenyl)-N,N-dimethyl-3-(3-pyridyl)allylamine 
• 60324-59-6 Nomelidine 
• 91671-08-8 Bis-[(Z)-3-(4-bromo-phenyl)-3-pyridin-3-yl-allyl]-methyl-amine 
• 82589-78-4 (Z)-3-(4-bromophenyl)-N-hydroxy-N-methyl-3-(3-pyridyl)allylamine 

Relevant articles and documents

Metabolites of the Pyridylallylamine Zimelidine Syntheses via α,β-Unsaturated Aldehydes with Conservation of Stereochemistry

Some tentative metabolites and metabolic intermediates of (Z)-3-(4-bromophenyl)-N,N-dimethyl-3-(3-pyridyl)allylamine (1, zimelidine) were synthesized. (Z)-3-(4-Bromophenyl)-3-(3-pyridyl)-2-propenal (8) and its N-oxide (15) were used in syntheses of N-methyl-hydroxylamines (17, 18), the pyridyl N-oxide of zimelidine (16) and a nitrone (19).The nitrone was also formed by oxidation of the allylic carbon of the corresponding N-methylhydroxylamine 17 with silver oxide.The compounds were diastereomerically pure and shown to possess the Z-configuration by means of UV and 1H NMR.