77542-08-6Relevant articles and documents
Synthesis of (Z)-α-Trifluoromethyl Alkenyl Triflate: A Scaffold for Diverse Trifluoromethylated Species
Zhao, Yilong,Zhou, Yuhan,Liu, Juan,Yang, Dongmei,Tao, Liang,Liu, Yang,Dong, Xiaoliang,Liu, Jianhui,Qu, Jingping
, p. 4797 - 4806 (2016/07/06)
An efficient method for the synthesis of (Z)-selective α-trifluoromethyl alkenyl triflates is described. As an important fluorinated building block, it is utilized successfully for the synthesis of various trifluoromethyl derivatives such as diarylethylen
One-pot multistep synthesis of trisubstituted alkenes from N -tosylhydrazones and alcohols
Sha, Qiang,Wei, Yunyang
, p. 2353 - 2361 (2014/11/08)
A one-pot procedure for the synthesis of trisubstituted alkenes from N-tosylhydrazones and alcohols is reported. This procedure combines the aerobic oxidation reaction and Wittig reaction in one pot, which avoids using of environmentally toxic oxidants and isolation of the intermediates. The simple procedure makes it very attractive for the synthesis of trisubstituted alkenes when alcohols are used as starting materials. A variety of trisubstituted alkenes as well as trifluoromethyl-substituted alkenes were obtained in moderate to good yields (up to 84%) with good E-selectivity (up to 99%). Georg Thieme Verlag Stuttgart.New York.
Pd-carbene migratory insertion: Application to the synthesis of trifluoromethylated alkenes and dienes
Wang, Xi,Xu, Yan,Deng, Yifan,Zhou, Yujing,Feng, Jiajie,Ji, Guojing,Zhang, Yan,Wang, Jianbo
supporting information, p. 961 - 965 (2014/02/14)
Pd-catalyzed cross-coupling of halides with CF3-substituted diazo compounds or N-tosylhydrazones has been explored for the synthesis of CF3-substituted alkenes and 1,3-butadienes. Pd-carbene migratory insertion plays the key role in these transformations. Copyright
