777-82-2

Basic information

• Product Name: Trimethyl(4-phenylbutyl)silane
• Synonyms: Trimethyl(4-phenylbutyl)silane
• CAS NO: 777-82-2
• Molecular Formula: C₁₃H₂₂Si
• Molecular Weight: 206.4
• Mol File: 777-82-2.mol
• Article Data: 4

Chemical Properties

• Appearance: /
• CAS DataBase Reference: Trimethyl(4-phenylbutyl)silane(CAS DataBase Reference)
• NIST Chemistry Reference: Trimethyl(4-phenylbutyl)silane(777-82-2)
• EPA Substance Registry System: Trimethyl(4-phenylbutyl)silane(777-82-2)

Safety Data

• Hazardous Substances Data: 777-82-2(Hazardous Substances Data)

Usage

General Description

Trimethyl(4-phenylbutyl)silane is a chemical compound with the formula C13H20Si. It is a silane derivative that features a silicon atom bonded to three methyl groups and a 4-phenylbutyl group. Trimethyl(4-phenylbutyl)silane is commonly used as a precursor in the synthesis of various organosilicon compounds, particularly in the production of silicone polymers and silicone resins. Trimethyl(4-phenylbutyl)silane is a clear, colorless liquid with a slight aromatic odor and is typically stored in a sealed container away from heat and moisture. This chemical is known to be highly flammable and may release toxic fumes when exposed to high temperatures, so proper safety precautions should be taken when handling and storing it.

Upstream product

• 75-77-4 chloro-trimethyl-silane 
• 13633-25-5 1-Bromo-4-phenylbutane 
• 768-56-9 4-Phenylbut-1-ene 
• 75-16-1 methylmagnesium bromide 
• 917-54-4 methyllithium 
• 92741-12-3 1,1-dimethyl-2-phenyl-1-silacyclopentane 
• 768-33-2 phenyldimethylsilyl chloride 
• 109153-94-8 4-Phenyl-4-(trimethylsilyl)butyllithium 
• 109-99-9 tetrahydrofuran 
• 60-29-7 diethyl ether 
• 42808-98-0 phenethyllithium 
• 32328-67-9 1-phenyl-4-(chlorodimethylsilyl)-butane 
• 92741-13-4 1-bromo-1-phenyl-4-(chlorodimethylsilyl)-butan 
• 3360-41-6 4-phenyl-butan-1-ol 

Relevant articles and documents

Catalytic synthesis of n-alkyl arenes through alkyl group cross-metathesis

n-Alkyl arenes were prepared in a one-pot tandem dehydrogenation/olefin metathesis/hydrogenation sequence directly from alkanes and ethylbenzene. Excellent selectivity was observed when (tBuPCP)IrH2 was paired with tungsten monoaryloxide pyrrolide complexes such as W(NAr)(C 3H6)(pyr)(OHIPT) (1a) [Ar = 2,6-i-Pr2C 6H3; pyr = pyrrolide; OHIPT = 2,6-(2,4,6-i-Pr 3C6H2)2C6H3O]. Complex 1a was also especially active in n-octane self-metathesis, providing the highest product concentrations reported to date. The thermal stability of selected olefin metathesis catalysts allowed elevated temperatures and extended reaction times to be employed.

RINGOEFFNUNG UND METALLIERUNG VON 1,1-DIMETHYL-2-PHENYL-SILACYCLOPENTAN UNTER DEM EINFLUSS VON METHYLLITHIUM IN TETRAHYDROFURAN

In contrast to 1-phenylethyllithium, which reacts as a base, methyllithium attacks the silicon atom of 1,1-dimethyl-2-phenyl-silacyclopentane (7) as a nucleophile whereby ring-opening takes place presumably via an ate-complex intermediate.The primarily fo