92741-13-4Relevant articles and documents
RINGOEFFNUNG UND METALLIERUNG VON 1,1-DIMETHYL-2-PHENYL-SILACYCLOPENTAN UNTER DEM EINFLUSS VON METHYLLITHIUM IN TETRAHYDROFURAN
Maercker, Adalbert,Stoetzel, Reinhard
, p. C40 - C46 (2007/10/02)
In contrast to 1-phenylethyllithium, which reacts as a base, methyllithium attacks the silicon atom of 1,1-dimethyl-2-phenyl-silacyclopentane (7) as a nucleophile whereby ring-opening takes place presumably via an ate-complex intermediate.The primarily fo