77920-99-1

Basic information

• Product Name: (Z)-ethyl 4,4-dimethyl-3-phenylpent-2-enoate
• Synonyms: (Z)-ethyl 4,4-dimethyl-3-phenylpent-2-enoate
• CAS NO: 77920-99-1
• Molecular Weight: 232.323
• Mol File: 77920-99-1.mol
• Article Data: 2

Chemical Properties

• CAS DataBase Reference: (Z)-ethyl 4,4-dimethyl-3-phenylpent-2-enoate(CAS DataBase Reference)
• NIST Chemistry Reference: (Z)-ethyl 4,4-dimethyl-3-phenylpent-2-enoate(77920-99-1)
• EPA Substance Registry System: (Z)-ethyl 4,4-dimethyl-3-phenylpent-2-enoate(77920-99-1)

Safety Data

• Hazardous Substances Data: 77920-99-1(Hazardous Substances Data)

Upstream product

• 1474-78-8 triethyl phosphonoformate 
• 938-16-9 2,2-dimethylpropiophenone 
• 867-13-0 diethoxyphosphoryl-acetic acid ethyl ester 

Downstream Products

• 384333-58-8 (Z)-4,4-dimethyl-3-phenylpent-2-en-1-ol 

Relevant articles and documents

Iridium-catalyzed asymmetric isomerization of primary allylic alcohols

Nothing to sm(Ir)k at: Under appropriate reaction conditions, iridium hydride catalysts promote the isomerization of primary allylic alcohols. The best catalysts, like (R)-1 (P green, O red, N blue, Ir yellow), deliver the desired chiral aldehydes with excellent enantioselectivity and good yields. Mechanistic hypotheses have been developed on the basis of preliminary investigations.