78386-47-7

Basic information

• Product Name: tropan-2β-yl toluene-p-sulphonate
• Synonyms: tropan-2β-yl toluene-p-sulphonate
• CAS NO: 78386-47-7
• Molecular Weight: 295.403
• Mol File: 78386-47-7.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: tropan-2β-yl toluene-p-sulphonate(CAS DataBase Reference)
• NIST Chemistry Reference: tropan-2β-yl toluene-p-sulphonate(78386-47-7)
• EPA Substance Registry System: tropan-2β-yl toluene-p-sulphonate(78386-47-7)

Safety Data

• Hazardous Substances Data: 78386-47-7(Hazardous Substances Data)

Upstream product

• 123686-89-5 (1RS)-8-methyl-8-azabicyclo[3.2.1]oct-2-ene-2-carbonitrile 
• 78386-54-6 phenyl 2β,3β-epoxy-8-azabicycl<3.2.1>octane-8-carboxylate 
• 78386-53-5 phenyl 8-azabicycl<3.2.1>oct-2-ene-8-carboxylate 
• 99020-85-6 (+/-)-Anhydroecgonine amide 
• 529-18-0 tropidine 
• 13612-59-4 cyclohepta-2,4,6-triene-1-carbonitrile 
• 78477-91-5 8-methyl-8-azabicyclo[3.2.1]octan-2-one 
• 98-59-9 p-toluenesulfonyl chloride 
• 13466-55-2 tropan-2β-ol 

Relevant articles and documents

Solvolytic Rearrangements of Azabicyclic Compounds. Part 2. Kinetics

Rates of solvolysis in aqueous ethanol and aqueous dioxan of three 2-exo-chloroazabicycloalkanes have been studied and first-order rare constants are derived and compared with published values for analogous compounds.Anchimeric assistance by the bridge N-atom is evidently not important in the rate-controlling step in these rearrangements, though it may occur to a minor extent in the case of 2-exo-chloro-7-methyl-7-azanorbornane.Solvolytic results for tropan-2β-yl toluene-p-sulphonate in aqueous ethanol and aqueous acetone mixtures are also reported and compared with literature data for the carbobicyclic and oxabicyclic analogues.