79135-54-9

Basic information

• Product Name: Benzene, 1,1'-(1,2-ethenediyl)bis[4-(1,1-dimethylethyl)-
• CAS NO: 79135-54-9
• Molecular Formula: C22H28
• Molecular Weight: 292.464
• Mol File: 79135-54-9.mol
• Article Data: 21

Chemical Properties

• CAS DataBase Reference: Benzene, 1,1'-(1,2-ethenediyl)bis[4-(1,1-dimethylethyl)-(CAS DataBase Reference)
• NIST Chemistry Reference: Benzene, 1,1'-(1,2-ethenediyl)bis[4-(1,1-dimethylethyl)-(79135-54-9)
• EPA Substance Registry System: Benzene, 1,1'-(1,2-ethenediyl)bis[4-(1,1-dimethylethyl)-(79135-54-9)

Safety Data

• Hazardous Substances Data: 79135-54-9(Hazardous Substances Data)

Upstream product

• 1710-98-1 p-tert-butyl benzoyl chloride 
• 18880-00-7 1-(bromomethyl)-4-(1,1-dimethylethyl)benzene 
• 19692-45-6 4-tert-butylbenzyl chloride 
• 61440-86-6 bis(4-tert-butylphenyl)acetylene 
• 79135-57-2 1,2-Dibromo-1,2-bis(p-tert-butylphenyl)ethane 
• 98-51-1 4-tert-butyltoluene 
• 22927-07-7 1,2-bis(4-tert-butylphenyl)ethane 
• 79135-53-8 1-Bromo-1,2-bis(p-tert-butylphenyl)ethane 
• 86439-83-0 DL-3,4-Bis(4-tert-butylphenyl)-2,2,5,5-tetramethylhexan 
• 345948-38-1 meso-3,4-Bis(4-tert-butylphenyl)-2,2,5,5-tetramethylhexan 
• 64-19-7 acetic acid 
• 138534-86-8 Toluene-4-sulfonic acid 2,2-bis-(4-tert-butyl-phenyl)-ethyl ester 
• 77387-64-5 1,2-bis((4-tert-butyl)phenyl)-2-hydroxyethanone 
• 1746-23-2 4-tert-Butylstyrene 

Downstream Products

• 1105044-16-3 (1S,2S)-1,2-bis(4-(tert-butyl)phenyl)ethane-1,2-diol 
• 639057-88-8 2,2'-methylenebis[(4S,5R)-4,5-di-(4-tert-butylphenyl)-2-oxazoline] 
• 939-97-9 4-tert-Butylbenzaldehyde 
• 26537-19-9 methyl 4-tert-butylbenzoate 
• 98-73-7 4-(1,1-dimethylethyl)benzoic acid 
• 79135-62-9 1,2-bis(4-(tert-butyl)phenyl)ethan-1-one 
• 61440-86-6 bis(4-tert-butylphenyl)acetylene 
• 22927-07-7 1,2-bis(4-tert-butylphenyl)ethane 
• 639057-82-2 (1R,2S)-2-azido-1,2-di-(4-tert-butylphenyl)ethan-1-ol 

Relevant articles and documents

A new role for sulfenate anions: Organocatalysis

(Chemical Equation Presented) The sulfenate anion is introduced for the first time as a catalyst and was found to facilitate the conversion of benzyl halides to trans-stilbenes. CPME=Cyclopentyl methyl ether.

AIR-STABLE NI(0)-OLEFIN COMPLEXES AND THEIR USE AS CATALYSTS OR PRECATALYSTS

The present invention relates to air stable, binary Ni(0)-olefin complexes and their use in organic synthesis.

Simpler and Cleaner Synthesis of Variously Capped Cobalt Nanocrystals Applied in the Semihydrogenation of Alkynes

Unlike the classical organometallic approach, we report here a synthetic pathway requiring no reducing sources or heating to produce homogeneous hexagonal-close-packed cobalt nanocrystals (Co NCs). Involving a disproportionation process, this simple and fast (6 min) synthesis is performed at room temperature in the presence of ecofriendly fatty alcohols to passivate Co NCs. Through a recycling step, the yield of Co NCs is improved and the waste generation is limited, making this synthetic route cleaner. After an easy exchange of the capping ligands, we applied them as unsupported catalysts in the stereoselective semihydrogenation of alkynes.