795275-76-2Relevant articles and documents
The asymmetric synthesis of (-)-pumiliotoxin C using tandem catalysis
Dijk, Ewold W.,Panella, Lavinia,Pinho, Pedro,Naasz, Robert,Meetsma, Auke,Minnaard, Adriaan J.,Feringa, Ben L.
, p. 9687 - 9693 (2007/10/03)
The potent neurotoxin (-)-pumiliotoxin C has been prepared in 8 steps starting from 2-cyclohexenone. Key steps are a tandem asymmetric conjugate addition-allylic substitution reaction and a tandem Heck-allylic substitution reaction. Graphical Abstract.