799267-93-9

Basic information

• Product Name: trans-2,3,4,6-tetra-O-benzyl-1-deoxy-1-(prop-1'-enyl)-α-D-galactopyranose
• Synonyms: trans-2,3,4,6-tetra-O-benzyl-1-deoxy-1-(prop-1'-enyl)-α-D-galactopyranose
• CAS NO: 799267-93-9
• Molecular Weight: 564.722
• Mol File: 799267-93-9.mol
• Article Data: 2

Chemical Properties

• CAS DataBase Reference: trans-2,3,4,6-tetra-O-benzyl-1-deoxy-1-(prop-1'-enyl)-α-D-galactopyranose(CAS DataBase Reference)
• NIST Chemistry Reference: trans-2,3,4,6-tetra-O-benzyl-1-deoxy-1-(prop-1'-enyl)-α-D-galactopyranose(799267-93-9)
• EPA Substance Registry System: trans-2,3,4,6-tetra-O-benzyl-1-deoxy-1-(prop-1'-enyl)-α-D-galactopyranose(799267-93-9)

Safety Data

• Hazardous Substances Data: 799267-93-9(Hazardous Substances Data)

Upstream product

• 133697-14-0 2,6-anhydro-7,8,9-trideoxy-D-glycero-L-galacto-non-8-enitol 
• 53263-18-6 allyl 2,3,4,6-tetra-O-acetyl-α-D-galactopyranoside 
• 100-39-0 benzyl bromide 
• 25878-60-8 D-galactose pentaacetate 
• 82659-55-0 3-(2',3',4',6'-tetra-O-benzyl-α-D-galactopyranosyl)prop-1-ene 

Downstream Products

• 799268-03-4 [(E)-(S)-1-((4S,5R)-2,2-Dimethyl-5-tetradecyl-[1,3]dioxolan-4-yl)-3-((2R,3S,4R,5S,6R)-3,4,5-tris-benzyloxy-6-benzyloxymethyl-tetrahydro-pyran-2-yl)-allyl]-carbamic acid tert-butyl ester 
• 799267-94-0 2,3,4,6-tetra-O-benzyl-1-deoxy-α-D-galactopyranosylethene 

Relevant articles and documents

Subtle stereochemical and electronic effects in iridium-catalyzed isomerization of C-allyl glycosides

Stereoselective isomerization of C-allyl glycosides into (E)-C-vinyl glycosides or (2)-exo-glycals was carried out in the presence of the cationic iridium(I) catalyst [(Ph2MeP)2Ir(cod)PF6]. The products of the isomerization were affected by the relative 1,2-stereochemical relationships and by the nature of the protecting groups. These effects are discussed along with a plausible reaction mechanism.