799267-94-0

Basic information

• Product Name: 2,3,4,6-tetra-O-benzyl-1-deoxy-α-D-galactopyranosylethene
• Synonyms: 2,3,4,6-tetra-O-benzyl-1-deoxy-α-D-galactopyranosylethene
• CAS NO: 799267-94-0
• Molecular Weight: 550.695
• Mol File: 799267-94-0.mol
• Article Data: 5

Chemical Properties

• CAS DataBase Reference: 2,3,4,6-tetra-O-benzyl-1-deoxy-α-D-galactopyranosylethene(CAS DataBase Reference)
• NIST Chemistry Reference: 2,3,4,6-tetra-O-benzyl-1-deoxy-α-D-galactopyranosylethene(799267-94-0)
• EPA Substance Registry System: 2,3,4,6-tetra-O-benzyl-1-deoxy-α-D-galactopyranosylethene(799267-94-0)

Safety Data

• Hazardous Substances Data: 799267-94-0(Hazardous Substances Data)

Upstream product

• 443915-85-3 trimethyl-[2-[(2R,3S,4R,5S,6R)-3,4,5-tribenzyloxy-6-(benzyloxymethyl)tetrahydropyran-2-yl]ethynyl]silane 
• 1824-94-8 methyl beta-D-galactopyranoside 
• 3866-62-4 2,3,4,6-tetra-O-benzyl-D-galactopyranosyl acetate 
• 100-39-0 benzyl bromide 
• 3879-79-6 methyl 2,3,4,6-tetra-O-benzyl α-D-galactopyranoside 
• 1826-67-1 vinyl magnesium bromide 
• 3396-99-4 methyl α-D-galactopyranoside 
• 53008-63-2 methyl 2,3,4,6-tetra-O-benzyl-α-D-galactopyranoside 
• 865880-61-1 C₃₇H₄₀O₅ 
• 53008-62-1 2,3,4,6-tetra-O-benzyl-α-D-galactopyranosyl iodide 
• 287962-77-0 (2R,3S,4R,5S,6R)-3,4,5-tribenzyloxy-2-(benzyloxymethyl)-6-ethynyl-tetrahydropyran 
• 74-85-1 ethene 
• 799267-93-9 trans-2,3,4,6-tetra-O-benzyl-1-deoxy-1-(prop-1'-enyl)-α-D-galactopyranose 

Downstream Products

• 918334-62-0 4-C-(2,3,4,6-tetra-O-benzyl-α-D-galactopyranosyl)-1-O-palmitoyl-2(S)-O-stearoyl-3-E-butene 
• 918334-61-9 4-C-(2,3,4,6-tetra-O-benzyl-α-D-galactopyranosyl)-1-O-palmitoyl-3-E-buten-2(S)-ol 
• 918334-60-8 4-C-(2,3,4,6-tetra-O-benzyl-α-D-galactopyranosyl)-3-E-butene-1,2(S)-di-O-acetate 
• 799268-03-4 [(E)-(S)-1-((4S,5R)-2,2-Dimethyl-5-tetradecyl-[1,3]dioxolan-4-yl)-3-((2R,3S,4R,5S,6R)-3,4,5-tris-benzyloxy-6-benzyloxymethyl-tetrahydro-pyran-2-yl)-allyl]-carbamic acid tert-butyl ester 

Relevant articles and documents

Practical Gram-Scale Synthesis of Either α- Or β-Anomer of C -Vinyl Glycosides

The synthesis C -vinyl glycosides, useful intermediates for the synthesis of C -glycoconjugates, was carried out on gram-scale by controlled reduction of the corresponding ethynyl derivatives in good to excellent yields in different carbohydrate series.

Efficient synthesis of a C-analogue of the immunogenic bacterial glycolipid BbGL2

(Diagram presented) Synthesis of a C-analogue of bacterial glycolipid BbGL2 is reported using Grignard reaction of in situ generated β-galactosyl iodide and subsequent olefin cross metathesis reaction of C-vinyl galactoside as key steps.

Efficient synthesis of α-C-galactosyl ceramide immunostimulants: Use of ethylene-promoted olefin cross-metathesis

(Chemical Equation Presented) Olefin cross-metathesis has been used to prepare α-C-galactosylceramide derivatives. The metathesis process merged vinyl and propenyl glycosides with vinyl derivatives of phytosphingosine. The use of ethylene enhanced the yie