82475-16-9

Basic information

• Product Name: 5,15-<2,2'-(dodecamethyleneoxy)diphenyl>:10,20-bis(o-hydroxyphenyl)porphyrin
• CAS NO: 82475-16-9
• Molecular Weight: 845.053
• Mol File: 82475-16-9.mol
• Article Data: 2

Chemical Properties

• CAS DataBase Reference: 5,15-<2,2'-(dodecamethyleneoxy)diphenyl>:10,20-bis(o-hydroxyphenyl)porphyrin(CAS DataBase Reference)
• NIST Chemistry Reference: 5,15-<2,2'-(dodecamethyleneoxy)diphenyl>:10,20-bis(o-hydroxyphenyl)porphyrin(82475-16-9)
• EPA Substance Registry System: 5,15-<2,2'-(dodecamethyleneoxy)diphenyl>:10,20-bis(o-hydroxyphenyl)porphyrin(82475-16-9)

Safety Data

• Hazardous Substances Data: 82475-16-9(Hazardous Substances Data)

Upstream product

• 25186-28-1 5,10,15,20-tetrakis(2-hydroxyphenyl)porphyrin 
• 3344-70-5 1,12-dibromododecane 

Relevant articles and documents

BOTH-FACES HINDERED PORPHYRINS. PART 2. SYNTHESIS AND CHARACTERIZATION OF INTERNALLY FIVE-CO-ORDINATED IRON(II)BASKET-HANDLE PORPHYRINS DERIVED FROM 5,10,15,20-TETRAKIS(O-HYDROXYPHENYL)PORPHYRIN

Compounds (9), so-called ether 'hanging base' porphyrins, derived from 5,10,15,20-tetrakis(o-hydroxyohenyl)porphyrin in which one of the faces is hindered by a pyridine-3,5-diylbisalkylene bridge and the other face is protected by an alkylene or an p-arylenebisalkylene chain have been synthesized following the concept of the 'basket handle' porphyrins (BHP).From an analysis of the 1H n.m.r. spectra of the iron(II) derivatives (20) at 34 degC, it has been determined that ca. 85percent were high-spin five-coordinated complexes (s=2).Despite the steric hindrance of the distal face, bimolecular associations typical for this class of compounds have been detected except for the most hindered (20c).An additional bispyridine 'basket handle' porphyrin (21) has been synthesized in order to study the dynamics of the pyridine chain.