826-08-4

Basic information

• Product Name: 2-Fluor-3t-phenyl-allylalkohol
• Synonyms: 2-Fluor-3t-phenyl-allylalkohol
• CAS NO: 826-08-4
• Molecular Weight: 152.168
• Mol File: 826-08-4.mol
• Article Data: 21

Chemical Properties

• CAS DataBase Reference: 2-Fluor-3t-phenyl-allylalkohol(CAS DataBase Reference)
• NIST Chemistry Reference: 2-Fluor-3t-phenyl-allylalkohol(826-08-4)
• EPA Substance Registry System: 2-Fluor-3t-phenyl-allylalkohol(826-08-4)

Safety Data

• Hazardous Substances Data: 826-08-4(Hazardous Substances Data)

Upstream product

• 58041-00-2 (Z)-2-fluoro-3-phenylacrylaldehyde 
• 118559-15-2 (E)-β-bromo-β-fluorostyrene 
• 350-90-3 (Z/E)-2-fluoro-3-phenylprop-2-enoic acid 
• 100-52-7 benzaldehyde 
• 350-99-2 ethyl (E/Z)-2-fluoro-3-phenylprop-2-enoate 
• 104-55-2 3-phenyl-propenal 
• 16084-65-4 2-chloro-2-fluoro-1-phenylcyclopropane 
• 141-53-7 sodium formate 
• 117141-34-1 C₉H₇ClF₄O 
• 1333325-95-3 C₁₀H₉F₃O₃S 
• 1479-22-7 ethyl 2-fluoro-3-oxo-3-phenylpropionate 
• 20397-59-5 ethyl (Z)-2-fluoro-3-phenylacrylate 
• 20397-61-9 (Z)-2-fluoro-3-phenylacrylic acid 

Downstream Products

• 141022-95-9 (2S)-2-fluoro-3-phenylpropan-1-ol 
• 122-97-4 3-Phenyl-1-propanol 
• 58041-00-2 (Z)-2-fluoro-3-phenylacrylaldehyde 

Relevant articles and documents

Palladium-Catalyzed Allyl-Allyl Reductive Coupling of Allylamines or Allylic Alcohols with H2as Sole Reductant

Catalytic carbon-carbon bond formation building on reductive coupling is a powerful method for the preparation of organic compounds. The identification of environmentally benign reductants is key for establishing an efficient reductive coupling reaction. Herein an efficient strategy enabling H2 as the sole reductant for the palladium-catalyzed allyl-allyl reductive coupling reaction is described. A wide range of allylamines and allylic alcohols as well as allylic ethers proceed smoothly to deliver the C-C coupling products under 1 atm of H2. Kinetic studies suggested that the dinuclear palladium species was involved in the catalytic cycle.

Cis-cinnamic acid analogue, gravitropism modifier (by machine translation)

[Problem] cinnamic acid or cinnamic acid analogue comprising adjusting agent gravitropism cis. [Solution] cinnamic acid and/or cinnamic acid as an active ingredient to adjust gravitropism cis edge agents, cinnamic acid edge is, for example obtained by reacting compounds of the following formula. (In the formula, R is a phenyl group. )Figure 6 [drawing] (by machine translation)

Ring-closing metathesis of fluoroalkenes toward the synthesis of fluorinated heterocycles containing an oxaza bond

This study reports the ring-closing metathesis reaction of bisolefins, including a reluctant fluoroalkenes, linked with oxaza moiety. The resulting heterocycles were produced in high yields under high diluting conditions disfavoring the homodimerization s