82873-58-3

Basic information

• Product Name: 1-acetyl-4-methyl-3-cyclohexen-1-ol
• Synonyms: 1-acetyl-4-methyl-3-cyclohexen-1-ol
• CAS NO: 82873-58-3
• Molecular Weight: 154.209
• Mol File: 82873-58-3.mol
• Article Data: 4

Chemical Properties

• CAS DataBase Reference: 1-acetyl-4-methyl-3-cyclohexen-1-ol(CAS DataBase Reference)
• NIST Chemistry Reference: 1-acetyl-4-methyl-3-cyclohexen-1-ol(82873-58-3)
• EPA Substance Registry System: 1-acetyl-4-methyl-3-cyclohexen-1-ol(82873-58-3)

Safety Data

• Hazardous Substances Data: 82873-58-3(Hazardous Substances Data)

Upstream product

• 42082-94-0 3-<(trimethylsilyl)oxy>-3-buten-2-one 
• 78-79-5 isoprene 
• 195200-21-6 2,4-Dinitro-benzoic acid 1-acetyl-4-methyl-cyclohex-3-enyl ester 
• 111945-66-5 1-Acetyl-4-methyl-3-cyclohexen-1-yl α-naphthoate 
• 111945-68-7 1-Acetyl-4-methyl-3-cyclohexen-1-yl β-naphthoate 
• 147331-99-5 1-(5-methyl-5-vinyl-tetrahydro-furan-2-yl)-ethanone 
• 111945-64-3 1-Acetyl-4-methyl-3-cyclohexen-1-yl p-nitrobenzoate 

Downstream Products

• 1234623-19-8 C₁₆H₁₇NO₂ 
• 1234623-20-1 C₁₆H₁₆ClNO₂ 
• 99-87-6 4-methylisopropylbenzene 
• 586-62-9 Terpinolene 
• 1195-32-0 1-methyl-4-isopropenylbenzene 
• 589-92-4 1-methylcyclohexan-4-one 
• 70150-56-0 (+/-)-4-hydroxy-4-methyl-2-cyclohexen-1-one 
• 122-00-9 para-methylacetophenone 
• 125228-98-0 1-(1-Chloro-4-methyl-cyclohex-3-enyl)-ethanone 
• 5259-65-4 4-methyl-3-cyclohexen-1-one 
• 55511-68-7 methyl 4-methylcyclohexa-1,4-dien-1-yl ketone 
• 24243-12-7 1-(4-methyl-1,3-cyclohe4xadienyl)-1-ethanone 
• 3419-02-1 4-methyl-1-isopropenylcyclohex-3-en-1-ol 
• 84295-55-6 racemic p-menth-1-ene-4,8-diol 

Relevant articles and documents

α-Acetyl- and α-Cyanovinyl 2,4-Dinitrophenyl Carboxylate as Useful Ketene Equivalents for the Diels-Alder Reaction

Two ketene equivalents (5 and 35) have been developed for use in the Diels-Alder reaction. These dienophiles exhibit a marked increase in reactivity in comparison with the more conventional acetoxyacrylonitrile. Conversions of the cycloadducts to the requisite ketones occurs under mild, and moderate to high yielding conditions.

REGIOSELECTIVITY OF DIELS-ALDER ADDITIONS OF 1-ACETYLVINYL ARENECARBOXYLATES

The Diels-Alder addition of "captodative" dienophiles 1-acetylvinyl arenecarboxylates 1b,1d and 1e to 1- and 2-substituted dienes was found highly regioselective.The rate and regioselectivity of this reaction were improved by Lewis acid catalysis.