84295-55-6

Basic information

• Product Name: 3-Cyclohexene-1-methanol, 1-hydroxy-alpha,alpha,4-trimethyl-
• CAS NO: 84295-55-6
• Molecular Weight: 170.252
• Mol File: 84295-55-6.mol
• Article Data: 5

Chemical Properties

• CAS DataBase Reference: 3-Cyclohexene-1-methanol, 1-hydroxy-alpha,alpha,4-trimethyl-(CAS DataBase Reference)
• NIST Chemistry Reference: 3-Cyclohexene-1-methanol, 1-hydroxy-alpha,alpha,4-trimethyl-(84295-55-6)
• EPA Substance Registry System: 3-Cyclohexene-1-methanol, 1-hydroxy-alpha,alpha,4-trimethyl-(84295-55-6)

Safety Data

• Hazardous Substances Data: 84295-55-6(Hazardous Substances Data)

Upstream product

• 586-62-9 Terpinolene 
• 5259-65-4 4-methyl-3-cyclohexen-1-one 
• 67-64-1 acetone 
• 75-16-1 methylmagnesium bromide 
• 82873-58-3 1-acetyl-4-methyl-3-cyclohexen-1-ol 
• 4584-23-0 2,2,6-trimethyl-1-oxa-spira[2.5]oct-ene 

Downstream Products

• 99-87-6 4-methylisopropylbenzene 
• 586-62-9 Terpinolene 
• 87129-26-8 2,8-dihydroxy-1,4-cineole 
• 87129-26-8 racemic 2β,8-dihydroxy-1,4-cineole 
• 19822-67-4 2,2,5-trimethylcyclohept-4-en-1-one 
• 35879-90-4 isokarahanaenone 

Relevant articles and documents

Selective Asymmetric Dihyroxylation of Polyenes

The asymmetric dihydroxylation procedure (AD) is applied to a variety of polyenes.In many cases excellent regioselectivities are obtained.The observed selectivities are rationalized in terms of electronic and/or steric inherent to the substrate, superimposed on the substrate's favorable or unfavorable interactions with the binding pocket of the AD ligand.Surprisingly, for medium and large ring olefins with trans-double bonds outstanding enantioselectivities are realized using the pyrimidine ligands.A hexaol of D3 symmetry is prepared from all trans cyclodecatriene.

1-Acetyl-4-methyl-3-cyclohexen-1-ol, a useful precursor in the synthesis of cyclic monoterpenes

A synthesis of monocyclic monoterpenes: p-mentha-1,8-dien-4-ol (1), terpinolene (4) and p,α-dimethylstyrene (5) from the titled compound 7, as a common precursor, is reported.

LEWIS ACID CATALYSED PINACOL REARRANGEMENT - A SHORT SYNTHESIS OF KARAHANAENONE

The pinacolic coupling reaction has been effectively used to prepare the unsymmetrical pinacol 2 and this key intermediate underwent a smooth ring enlargement to the monoterpene karahanaenone 3, an odoriferous constituent of Japanese hop and Cypress oil.