83027-14-9

Basic information

• Product Name: N-[2-[2-(benzylideneamino)phenyl]phenyl]-1-phenyl-methanimine
• CAS NO: 83027-14-9
• Molecular Formula: C₂₆H₂₀N₂
• Molecular Weight: 360.4504
• Mol File: 83027-14-9.mol
• Article Data: 2

Chemical Properties

• Boiling Point: 585.7°Cat760mmHg
• Flash Point: 301.5°C
• Density: 1.04g/cm³
• CAS DataBase Reference: N-[2-[2-(benzylideneamino)phenyl]phenyl]-1-phenyl-methanimine(CAS DataBase Reference)
• NIST Chemistry Reference: N-[2-[2-(benzylideneamino)phenyl]phenyl]-1-phenyl-methanimine(83027-14-9)
• EPA Substance Registry System: N-[2-[2-(benzylideneamino)phenyl]phenyl]-1-phenyl-methanimine(83027-14-9)

Safety Data

• Hazardous Substances Data: 83027-14-9(Hazardous Substances Data)

Upstream product

• 100-52-7 benzaldehyde 
• 1454-80-4 1,1'-biphenyl-2,2'-diamine 
• 2436-96-6 1-nitro-2-(2-nitrophenyl)benzene 

Downstream Products

• 873659-04-2 N,N'-dibenzyl-2,2'-diamino-1,1'-biphenyl 

Relevant articles and documents

Metathesis cleavage of an NN bond in benzo[: C] cinnolines and azobenzenes by triply-bonded ditungsten complexes

A metathesis reaction of a WW bond and an NN bond was observed by reacting a W-W triply-bonded W(iii)2 complex, (tBuO)3WW(OtBu)3 (1), with benzo[c]cinnoline derivatives to form biphenyl-linked dinuclear (imido)tungsten complexes 2-4. When azobenzene was used as the substrate, a trans to cis isomerization induced by blue-LED light was essential prior to the metathesis cleavage of the NN bond by the WW bond of (Me2N)2(TfO)WW(OTf)(NMe2)2 (6), affording the corresponding imido-bridged dinuclear tungsten complexes 7-9.