873659-04-2Relevant articles and documents
A sterically bulky cyclic thiourea as an efficient ligand for palladium-catalyzed aerobic oxidation of alcohols
Yang, Min,Yip, Kai-Tai,Pan, Jie-Hui,Chen, Ying-Chun,Zhu, Nian-Yong,Yang, Dan
, p. 3057 - 3060 (2008/02/13)
Sterically bulky N,N′-disubstituted cyclic thiourea ligand L1 has been demonstrated as an efficient ligand in palladium-catalyzed oxidation of alcohols using molecular oxygen as an oxidant. This new catalyst system has been applied to a wide variety of substrates such as benzylic alcohols, aliphatic secondary alcohols and allylic alcohols, producing the corresponding carbonyl compounds in good to excellent yields. Georg Thieme Verlag Stuttgart.