835903-40-7

Basic information

• Product Name: Benzene, 1,1'-[[1-(4-phenylcyclohexylidene)-1,3-propanediyl]bis(seleno)]bis-
• CAS NO: 835903-40-7
• Molecular Formula: C27H28Se2
• Molecular Weight: 510.439
• Mol File: 835903-40-7.mol
• Article Data: 3

Chemical Properties

• CAS DataBase Reference: Benzene, 1,1'-[[1-(4-phenylcyclohexylidene)-1,3-propanediyl]bis(seleno)]bis-(CAS DataBase Reference)
• NIST Chemistry Reference: Benzene, 1,1'-[[1-(4-phenylcyclohexylidene)-1,3-propanediyl]bis(seleno)]bis-(835903-40-7)
• EPA Substance Registry System: Benzene, 1,1'-[[1-(4-phenylcyclohexylidene)-1,3-propanediyl]bis(seleno)]bis-(835903-40-7)

Safety Data

• Hazardous Substances Data: 835903-40-7(Hazardous Substances Data)

Upstream product

• 1666-13-3 diphenyl diselenide 
• 147356-80-7 p-phenylcyclohexylidenecyclopropane 

Downstream Products

• 1073341-31-7 C₂₁H₂₂Se 

Relevant articles and documents

Iron salt, a cheap, highly efficient and environment-friendly metal catalyst for Se-Se bond cleavage and the further reaction with methylenecyclopropanes under mild conditions

FeCl3 was found to be a good catalyst in Se-Se bond cleavage. Further electrophilic additions to methylenecyclopropanes provide a convenient access to diphenylselenylcyclobutanes. Comparing with other Lewis acids, FeCl3 is much cheaper and the reaction conditions are milde and more tolerance to air and moisture.

Reaction of methylenecyclopropanes and diphenyl diselenide under visible-light irradiation

The reaction of methylenecyclopropanes with diphenyl diselenide promoted by visible light was investigated and a series of 2,4-diphenylselenyl-1-butenes was prepared under mild conditions. Interestingly, with the addition of oxidant such as dibenzoyl peroxide, 1-(phenylselenyl)cyclobutanols were obtained. Georg Thieme Verlag Stuttgart.