83909-75-5

Basic information

• Product Name: 2-methyl-3-phenyl-1,3-propane diol
• Synonyms: 2-methyl-3-phenyl-1,3-propane diol
• CAS NO: 83909-75-5
• Molecular Weight: 166.22
• Mol File: 83909-75-5.mol
• Article Data: 56

Chemical Properties

• CAS DataBase Reference: 2-methyl-3-phenyl-1,3-propane diol(CAS DataBase Reference)
• NIST Chemistry Reference: 2-methyl-3-phenyl-1,3-propane diol(83909-75-5)
• EPA Substance Registry System: 2-methyl-3-phenyl-1,3-propane diol(83909-75-5)

Safety Data

• Hazardous Substances Data: 83909-75-5(Hazardous Substances Data)

Upstream product

• 90106-95-9 Bromomethyl-dimethyl-(1-phenyl-allyloxy)-silane 
• 17226-81-2 ethyl (2R*,3R*)-3-hydroxy-2-methyl-3-phenylpropanoate 
• 16837-43-7 2-benzoylpropanal 
• 100-52-7 benzaldehyde 
• 4393-06-0 1-Phenyl-2-propen-1-ol 
• 123-38-6 propionaldehyde 
• 121745-98-0 Trifluoro-acetic acid 2-methyl-1-phenyl-allyl ester 
• 68913-18-8 3-acetoxy-2-methyl-3-phenylprop-1-ene 
• 103729-80-2 2-methyl-1-phenylprop-2-en-1-ol 
• 36482-33-4 (2RS,3SR)-3-hydroxy-2-methyl-3-phenyl-propionic acid hydrazide 
• 1895-97-2 2-methyl-3-phenylacrylic acid 
• 14366-86-0 (2RS, 3SR)-3-hydroxy-2-methyl-3-phenylpropanoic acid 
• 38614-40-3 2,4-dimethyl-penta-1,4-dien-3-ol 
• 15933-59-2 1,1,3,3-tetramethyldisilazane 

Downstream Products

• 7087-77-6 (1S,2S) /(1R,2R)-2-methyl-1-phenylpropane-1,3-diol 
• 14366-91-7 syn-2-methyl-1-phenyl-1,3-propanediol 
• 84784-83-8 3-hydroxy-2-methylpropiophenone methoxyethoxymethyl ether 
• 84784-81-6 erythro-2-methyl-3-phenyl-1,3-propanediol 1-methoxyethoxymethyl ether 
• 22821-07-4 2-(butylthio)benzo[d]oxazole 
• 2382-96-9 2-sulfanyl-1,3-benzoxazole 
• 16735-22-1 3-hydroxy-2-methylpropiophenone 
• 579-07-7 1-Phenylpropane-1,2-dione 
• 611-69-8 rac-2-methyl-1-phenylpropan-1-ol 
• 83909-76-6 erythro-1-Phenyl-2-methyl-3-tosyloxy-propanol 

Relevant articles and documents

Diastereo- and regioselective reactions of π-allyl molybdenum complexes with aldehydes

Remote heteroatom coordination to molybdenum promotes unprecedented selectivity in aldehyde allylation using unsymmetrically substituted allylic metal complexes. (C) 2000 Elsevier Science Ltd.

Copper-Catalyzed Stereospecific Hydroboration of Internal Allylic Alcohols

An effective Cu-catalyzed stereospecific hydroboration of aliphatic and aromatic 1,1,2-trisubstituted internal allylic alcohols has been reported. This reaction proceeds via a silyl ether transient protection of allylic alcohols and subsequent stereospecific hydroboration. Followed by an oxidative workup, an array of acyclic, cyclic, and heterocyclic 1,3-diols was synthesized in good to excellent yields with good functional group tolerance and excellent diastereomeric ratios (> 20:1).

Lewis Base-Promoted Ring-Opening 1,3-Dioxygenation of Unactivated Cyclopropanes Using a Hypervalent Iodine Reagent

A facile and effective system has been developed for the regio- and chemoselective ring-opening/electrophilic functionalization of cyclopropanes through C?C bond activation by [bis(trifluoroacetoxy)iodo]benzene with the aid of the Lewis basic promoter p-toluenesulfonamide. The p-toluenesulfonamide-promoted system works well for a wide range of cyclopropanes, resulting in the formation of 1,3-diol products in good yields and regioselectivity.