839676-86-7

Basic information

• Product Name: [Ru(cyclopentadienyl)(triphenylphosphine)2(O(1-naphthyl))]
• CAS NO: 839676-86-7
• Molecular Weight: 833.911
• Mol File: 839676-86-7.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: [Ru(cyclopentadienyl)(triphenylphosphine)2(O(1-naphthyl))](CAS DataBase Reference)
• NIST Chemistry Reference: [Ru(cyclopentadienyl)(triphenylphosphine)2(O(1-naphthyl))](839676-86-7)
• EPA Substance Registry System: [Ru(cyclopentadienyl)(triphenylphosphine)2(O(1-naphthyl))](839676-86-7)

Safety Data

• Hazardous Substances Data: 839676-86-7(Hazardous Substances Data)

Upstream product

• 32993-05-8 chloro(cyclopentadienyl)bis(triphenylphosphine)ruthenium (II) 
• 19402-71-2 potassium 1-naphtholate 

Relevant articles and documents

Acid-promoted hydrogen migration in (2-allylphenoxo)ruthenium(II) to form an η3-allyl complex

Treatment of RuCP[OC6H4(CH2CH=CH 2)-κ1O: η2C,C′](PPh 3) (3c) with a Bronsted acid (HX) such as 2-al-lylphenol results in facile migration of a benzylic proton to the aryloxide, giving the (η3-allyl)ruthenium(II) complex RuCp[CH2-CHCH(C 6H4OH-2)-η3 C,C′,C″](PPh 3) (Ac). Thermodynamic and kinetic studies suggest that 3c associates with acid to give 3c · HX, and further addition of HX to 3c · HX causes the C-H bond cleavage reaction to give 4c.