84051-33-2

Basic information

• Product Name: (2S,3R,6S)-6-((R)-1-(benzyloxy)prop-2-yl)-3-methyl-2-((E)-3-(trimethylsilyl)but-2-en-1-yl)cyclohexanone
• Synonyms: (2S,3R,6S)-6-((R)-1-(benzyloxy)prop-2-yl)-3-methyl-2-((E)-3-(trimethylsilyl)but-2-en-1-yl)cyclohexanone
• CAS NO: 84051-33-2
• Molecular Weight: 386.65
• Mol File: 84051-33-2.mol
• Article Data: 2

Chemical Properties

• CAS DataBase Reference: (2S,3R,6S)-6-((R)-1-(benzyloxy)prop-2-yl)-3-methyl-2-((E)-3-(trimethylsilyl)but-2-en-1-yl)cyclohexanone(CAS DataBase Reference)
• NIST Chemistry Reference: (2S,3R,6S)-6-((R)-1-(benzyloxy)prop-2-yl)-3-methyl-2-((E)-3-(trimethylsilyl)but-2-en-1-yl)cyclohexanone(84051-33-2)
• EPA Substance Registry System: (2S,3R,6S)-6-((R)-1-(benzyloxy)prop-2-yl)-3-methyl-2-((E)-3-(trimethylsilyl)but-2-en-1-yl)cyclohexanone(84051-33-2)

Safety Data

• Hazardous Substances Data: 84051-33-2(Hazardous Substances Data)

Upstream product

• 100-39-0 benzyl bromide 
• 13834-07-6 (1R,3R,4S,8R)-9-hydroxy-p-menthol 
• 143949-25-1 (R,E)-ethyl 2,6-dimethyl-8-oxooct-2-enoate 
• 2385-77-5 (R)-Citronellal 
• 84051-31-0 <1R>-5(R)-methyl-2(S)-<1(R)-methyl-2-(phenylmethoxy)ethyl>cyclohexanol 
• 84051-29-6 (1S,2R,4R)-1-Isopropenyl-2-methoxymethoxy-4-methyl-cyclohexane 
• 7786-67-6 isopulegol 
• 52685-51-5 (E)-(3-iodo-1-methyl-1-propenyl)-trimethylsilane 
• 84051-32-1 (2S,5R)-2-((R)-1-(benzyloxy)propan-2-yl)-5-methylcyclohexanone 
• 84051-30-9 (R)-2-((1S,2R,4R)-2-Methoxymethoxy-4-methyl-cyclohexyl)-propan-1-ol 

Downstream Products

• 93913-62-3 3(R)-methyl-6(S)-<1(R)-methyl-2-(phenylmethoxy)ethyl>-2(S)-(3-oxobutyl)cyclohexanone 
• 84051-34-3 (1S,2S,3R,6S)-6-((R)-2-Benzyloxy-1-methyl-ethyl)-1-((R)-methoxy-trimethylsilanyl-methyl)-3-methyl-2-((E)-3-trimethylsilanyl-but-2-enyl)-cyclohexanol 
• 84064-31-3 (1S,2S,3R,6S)-6-((R)-2-Benzyloxy-1-methyl-ethyl)-1-((S)-methoxy-trimethylsilanyl-methyl)-3-methyl-2-((E)-3-trimethylsilanyl-but-2-enyl)-cyclohexanol 

Relevant articles and documents

Asymmetric synthesis of dihydroartemisinic acid through intramolecular Stetter reaction

A short and concise formal synthesis of enantiopure dihydroartemisinic acid from (R)-citronellal is described in this article. Intramolecular version of asymmetric Stetter reaction using Rovis aminoindane based NHC catalyst was explored to access the core