841303-89-7

Basic information

• Product Name: bis(η5-cyclopentadienyl)(di(3-methylindol-2-yl)phenylmethane)zirconium
• CAS NO: 841303-89-7
• Molecular Weight: 641.968
• Mol File: 841303-89-7.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: bis(η5-cyclopentadienyl)(di(3-methylindol-2-yl)phenylmethane)zirconium(CAS DataBase Reference)
• NIST Chemistry Reference: bis(η5-cyclopentadienyl)(di(3-methylindol-2-yl)phenylmethane)zirconium(841303-89-7)
• EPA Substance Registry System: bis(η5-cyclopentadienyl)(di(3-methylindol-2-yl)phenylmethane)zirconium(841303-89-7)

Safety Data

• Hazardous Substances Data: 841303-89-7(Hazardous Substances Data)

Upstream product

• 109-99-9 tetrahydrofuran 
• 1291-32-3 zirconocene dichloride 
• 95816-67-4 bis(3-methylindolyl)phenylmethane 

Relevant articles and documents

Deprotonated diindolylmethanes as dianionic analogues of scorpionate bis(pyrazolyl)borate ligands: Synthesis and structural characterization of representative titanocene and zirconocene complexes

Deprotonation of di(3-methylindol-2-yl)phenylmethane (L2H 2) or 2-methoxyphenyldi(3-methylindol-2-yl)methane(L2′H2) with two equivalents of nBuLi, followed by reactions with Cp 2TiCl2 or Cp2ZrCl2 yielded complexes Cp2TiL2(1),Cp2TiL2′(2),Cp2ZrL2(3)andCp2ZrL2′(4). Compounds 1-4 were characterized by NMR spectroscopy, and compounds 1, 3, and 4 were further analyzed by X-ray crystallography and elemental analysis. The molecular structures of 1, 3, and 4 illustrate that chelating di(3-methylindol-2-yl) methanes have a structural relationship to coordinated bis(pyrazolyl)borates.