84247-82-5

Basic information

• Product Name: Silane, trimethyl(4-phenyl-1,3-butadienyl)-, (Z,E)-
• CAS NO: 84247-82-5
• Molecular Formula: C13H18Si
• Molecular Weight: 202.371
• Mol File: 84247-82-5.mol
• Article Data: 5

Chemical Properties

• CAS DataBase Reference: Silane, trimethyl(4-phenyl-1,3-butadienyl)-, (Z,E)-(CAS DataBase Reference)
• NIST Chemistry Reference: Silane, trimethyl(4-phenyl-1,3-butadienyl)-, (Z,E)-(84247-82-5)
• EPA Substance Registry System: Silane, trimethyl(4-phenyl-1,3-butadienyl)-, (Z,E)-(84247-82-5)

Safety Data

• Hazardous Substances Data: 84247-82-5(Hazardous Substances Data)

Upstream product

• 61518-50-1 1,3-bis(trimethylsilyl)prop-1-enyl-lithium 
• 17891-78-0 2,2,6,6-tetramethyl-2,6-disila-3-heptene 
• 21087-29-6 trans-3-phenylprop-2-enyl chloride 
• 2612-42-2 (dibromomethyl)trimethylsilane 
• 106-95-6 allyl bromide 
• 14371-10-9 (E)-3-phenylpropenal 
• 100-52-7 benzaldehyde 
• 18178-59-1 (E)-1,2-bis(trimethylsilyl)ethene 
• 42599-24-6 E-styryl iodide 
• 3739-98-8 triphenyl(trimethylsilylmethyl)phosphonium iodide 

Relevant articles and documents

The Synthesis of Alkenes from Carbonyl Compounds and Carbanions α to Silicon. Stereoselective Synthesis of 1-Trimethylsilylbuta-1,3-dienes

Reactions of aldehydes with the 1,3-bis(trimethylsilyl)propenyl anion in the presence of magnesium bromide or trimethyl borate give stereoselectively the alcohols (2) which can be transformed stereospecifically to either (1E,3E)- or (1E,3Z)-1-trimethylsilylbuta-1,3-dienes.

Preparation of silyl-substituted dizinciomethanes and their reactions with electrophiles

Silyl-substituted bis(bromozincio)methanes (RMe2Si-CH(ZnBr)2; R = Me, Ph, and p-MeO-C6H4), prepared from the corresponding dibromides by Pb catalyzed reaction with zinc, reacted stepwise with two different electrophiles, R1X and E+, yielding R1- CH(SiMe2R)-E.

SYNTHESIS OF χ,δ-UNSATURATED α-AMINO ACIDS FROM ALLYLSILANES AND GLYCIDYL CATION EQUIVALENTS

The synthesis of a series of χ,δ-unsaturated N-protected α-amino acid methylesters from the coupling of different allylsilanes and glycidyl cation equivalents 6 and 7 is described.Reactions with methoxyglycine derivative 6 are induced with BF3*OEt2; in the case of chloroglycine derivative 7 SnCl4 is used as Lewis acid.Reactions are fully regioselective, but show low stereoselectivity.The conversion of the reaction products into unprotected α-amino acids is described for two cases.