84434-11-7

Basic information

• Product Name: Ethyl (2,4,6-trimethylbenzoyl) phenylphosphinate
• Synonyms: 4-BENZORESORCINOL;4-BENZOYLRESORCINOL;2,4,6-trimethylbenzoylethoxyphenylphosphine oxide;2,4,6-TRIMETHYLBENZOYLPHENYLPHOSPHINIC ACID ETHYL ESTER;DIHYDROXYBENZOPHENONE(2,4-);ethyl (2,4,6-trimethylbenzoyl) phenylphosphinate;BENZOPHENONE-1;Phenyl(2,4,6-trimethylbenzoyl)phosphinic acid ethyl ester
• CAS NO: 84434-11-7
• Molecular Formula: C₁₈H₂₁O₃P
• Molecular Weight: 316.33
• EINECS: 282-810-6
• Mol File: 84434-11-7.mol
• Article Data: 7

Chemical Properties

• Melting Point: 144.5-147 °C(lit.)
• Boiling Point: 456.023 °C at 760 mmHg
• Flash Point: 242.878 °C
• Appearance: /
• Density: 1.14
• Vapor Pressure: 0mmHg at 25°C
• Refractive Index: 1.549
• Storage Temp.: under inert gas (nitrogen or Argon) at 2-8°C
• Solubility: 71.8g/L in organic solvents at 20 ℃
• Water Solubility: 35mg/L at 25℃
• CAS DataBase Reference: Ethyl (2,4,6-trimethylbenzoyl) phenylphosphinate(CAS DataBase Reference)
• NIST Chemistry Reference: Ethyl (2,4,6-trimethylbenzoyl) phenylphosphinate(84434-11-7)
• EPA Substance Registry System: Ethyl (2,4,6-trimethylbenzoyl) phenylphosphinate(84434-11-7)

Safety Data

• Hazard Codes: Xi
• Statements: 36
• Safety Statements: 26
• WGK Germany: 2
• RTECS: DJ0700000
• Hazardous Substances Data: 84434-11-7(Hazardous Substances Data)

Usage

Description

Ethyl (2,4,6-trimethylbenzoyl) phenylphosphinate, also known as Photoinitiator TPO-L, is a liquid photoinitiator that is specifically designed for low yellowing and low odor formulations. It is a versatile compound that offers a range of benefits in various applications due to its unique chemical properties.

Uses

Used in Printing Industry:
Ethyl (2,4,6-trimethylbenzoyl) phenylphosphinate is used as a photoinitiator in screen printing inks for its ability to provide low yellowing and low odor results, ensuring high-quality prints with minimal environmental impact.
Ethyl (2,4,6-trimethylbenzoyl) phenylphosphinate is also used as a photoinitiator in lithographic printing inks, contributing to the production of clear and sharp prints with reduced odor and yellowing.
Used in Flexographic Printing Industry:
In flexo printing inks, Ethyl (2,4,6-trimethylbenzoyl) phenylphosphinate serves as a photoinitiator that helps in achieving high-quality prints with minimal yellowing and odor, making it suitable for a wide range of applications.
Used in Photoresist and Varnish Industry:
Ethyl (2,4,6-trimethylbenzoyl) phenylphosphinate is used as a photoinitiator in photoresists and varnishes, offering low yellowing and low odor properties that are essential for creating high-quality coatings and resists.
Used in Printing Plate Industry:
In the production of printing plates, Ethyl (2,4,6-trimethylbenzoyl) phenylphosphinate is utilized as a photoinitiator to ensure the creation of plates with excellent print quality, low yellowing, and minimal odor.
Overall, Ethyl (2,4,6-trimethylbenzoyl) phenylphosphinate is a valuable compound in the printing and coating industries due to its role as a photoinitiator that promotes low yellowing and low odor formulations, enhancing the quality and sustainability of various products.

Flammability and Explosibility

Nonflammable

InChI:InChI=1/C18H21O3P/c1-5-21-22(20,16-9-7-6-8-10-16)18(19)17-14(3)11-13(2)12-15(17)4/h6-12H,5H2,1-4H3

Upstream product

• 644-97-3 Dichlorophenylphosphine 
• 1779-48-2 phenylphosphinic acid 
• 487-68-3 mesytaldehyde 
• 64-67-5 diethyl sulfate 
• 1638-86-4 diethyl phenylphosphonite 
• 81759-79-7 2,2,2-trichloro-1-(2,4,6-trimethylphenyl)ethan-1-one 
• 71-43-2 benzene 
• 172487-18-2 ethyl Phenylphosphinate 
• 33642-96-5 ethyl trimethylsilyl phenylphosphonite 
• 938-18-1 mesitylene-2-carboxylic acid chloride 
• 64-17-5 ethanol 
• 1754-49-0 diethyl phenylphosphonate 
• 824-72-6 P,P-dichlorophenylphosphine oxide 
• 108-90-7 chlorobenzene 

Downstream Products

• 85073-12-7 sodium (2,4,6-trimethylbenzoyl)phenylphosphine oxide 
• 85073-19-4 lithium (2,4,6-trimethylbenzoyl)phenylphosphine oxide 

Relevant articles and documents

High performance liquid phase continuous automatic production and co-production technology of organic phosphine compound

The invention relates to the field of photocuring functional new material chemicals, and discloses a high performance liquid phase streamline type continuous automatic production technology of an acylphosphine oxide organic phosphine compound for the first time, which not only can produce a single specific target product, but also can co-produce a product mixture of two or more than two of the products of the type. The process technology has outstanding low-cost economic competitiveness and environment-friendly characteristics for large-scale manufacturing of target products. The target product comprises sym-trimethylbenzoyl diphenyl phosphine oxide (also known as 2, 4, 6-trimethylbenzoyl diphenyl phosphine oxide, trade name TPO), sym-trimethylbenzoyl phenyl ethyl phosphonate (trade name TPO-L) and structural analogues thereof, and a mixture of the sym-trimethylbenzoyl diphenyl phosphine oxide and the sym-trimethylbenzoyl phenyl ethyl phosphonate. The organic phosphine compound is an olefinic bond-containing (C=C) unsaturated radiation polymerization system photoinitiator and/or flame retardant and the like with wide application.

Chlorosilane-Catalyzed Coupling of Hydrogen Phosphine Oxides with Acyl Chlorides Generating Acylphosphine Oxides

We report a new method for the synthesis of acylphosphine oxides by the direct coupling of hydrogen phosphine oxides and acyl chlorides mediated by chlorosilanes. This new protocol is greener and safer, because it precludes the generation of volatile haloalkanes and the use of oxidants employed in the conventional methods. Moreover, moisture-unstable acylphosphine oxides that are difficult to prepare via the conventional methods can be generated using this new method.

Preparation method for high-purity ethyl (2,4,6-trimethylbenzoyl)phenylphosphinate

The invention discloses a preparation method for high-purity ethyl (2,4,6-trimethylbenzoyl)phenylphosphinate. The preparation method comprises the following concrete steps: reacting phenylphosphinate with aromatic aldehyde so as to prepare an intermediate, subjecting the intermediate to catalytic oxidation so as to obtain benzoylphenylphosphinic acid and subjecting benzoylphenylphosphinic acid and diethyl sulfate to an ethylation reaction so as to obtain ethyl (2,4,6-trimethylbenzoyl)phenylphosphinate. According to the invention, raw materials have high quality and stable properties; by-produced impurities produced during synthesis of ethyl (2,4,6-trimethylbenzoyl)phenylphosphinate can be removed through neutralization, and ethyl (2,4,6-trimethylbenzoyl)phenylphosphinate with a purity of higher than 99.0%, which meets market demands for the high-purity photoinitiator ethyl (2,4,6-trimethylbenzoyl)phenylphosphinate.