84565-67-3

Basic information

• Product Name: Benzene, 1-(1,1-dimethyl-2-propenyl)-3-methoxy-
• CAS NO: 84565-67-3
• Molecular Formula: C12H16O
• Molecular Weight: 176.258
• Mol File: 84565-67-3.mol
• Article Data: 6

Chemical Properties

• CAS DataBase Reference: Benzene, 1-(1,1-dimethyl-2-propenyl)-3-methoxy-(CAS DataBase Reference)
• NIST Chemistry Reference: Benzene, 1-(1,1-dimethyl-2-propenyl)-3-methoxy-(84565-67-3)
• EPA Substance Registry System: Benzene, 1-(1,1-dimethyl-2-propenyl)-3-methoxy-(84565-67-3)

Safety Data

• Hazardous Substances Data: 84565-67-3(Hazardous Substances Data)

Upstream product

• 10365-98-7 3-methoxyphenylboronic acid 
• 556-82-1 3-methyl-2-buten-1-ol 
• 32454-15-2 2-methyl-2-(m-methoxyphenyl)-1-propanal 
• 84565-80-0 1-(1,1-Dimethyl-allyl)-3-methoxy-cyclohexa-2,5-dienecarboxylic acid 
• 1779-49-3 Methyltriphenylphosphonium bromide 
• 766-85-8 3-methoxy-1-iodobenzene 
• 114067-34-4 (3-methyl-2-butenyl)trifluorosilane 

Downstream Products

• 40463-03-4 2-methyl-4-(m-methoxyphenyl)-1-butene 
• 72390-19-3 m-Methoxybenzyl tert-butyl ether 
• 90433-21-9 1,1-Dimethyl-2-(m-methoxyphenyl)cyclopropane 
• 18272-91-8 1-methoxy-3-(3-methylbut-2-en-1-yl)benzene 
• 155820-00-1 1-methoxy-3-tert-pentylbenzene 

Relevant articles and documents

Palladium-catalyzed prenylation of (hetero)aryl boronic acids

Prenyl or dimethylallyl groups are common structural motifs in natural products and small molecule therapeutics. In this report, we describe a palladium-catalyzed method for the cross-coupling of aryl and heteroaryl boronic acids with prenyl alcohol. Catalyst systems based on dialkylbiaryl phosphines were highly active for this transformation. These supporting ligands provided opportunities for tuning the efficiency and regioselectivity of carbon–carbon bond formation. In addition, this method was further extended to the cross-coupling of symmetrical allylic alcohols with aryl boronic acids.

CHROMENE DERIVATIVES AS ANTI-INFLAMMATORY AGENTS

The subject invention concerns methods and compounds that have utility in the treatment of a condition associated with cyclooxygenase-2 mediated disorders. Compounds of particular interest are benzopyrans and their analogs defined by formula (I). Wherein Z, X, R1, R2, R3, and R4 are as described in the specification.

Reactivity of Aryl Vinyl Di-?-methane Systems. Mechanistic and Exploratory Organic Photochemistry

The di-?-methane rearrangement of a series of meta and para substituted arylvinylmethane reactants was investigated with the aim of determiningthe patterns of reactivity in systems in which initial excitation is localized in the aryl moiety.Thus the photo