84584-97-4

Basic information

• Product Name: 3H-Indol-3-one, 1,2-dihydro-1-methyl-2-(phenylmethylene)-
• CAS NO: 84584-97-4
• Molecular Formula: C16H13NO
• Molecular Weight: 235.285
• Mol File: 84584-97-4.mol
• Article Data: 3

Chemical Properties

• CAS DataBase Reference: 3H-Indol-3-one, 1,2-dihydro-1-methyl-2-(phenylmethylene)-(CAS DataBase Reference)
• NIST Chemistry Reference: 3H-Indol-3-one, 1,2-dihydro-1-methyl-2-(phenylmethylene)-(84584-97-4)
• EPA Substance Registry System: 3H-Indol-3-one, 1,2-dihydro-1-methyl-2-(phenylmethylene)-(84584-97-4)

Safety Data

• Hazardous Substances Data: 84584-97-4(Hazardous Substances Data)

Upstream product

• 57056-93-6 N-methyl-2-iodoaniline 
• 536-74-3 phenylacetylene 
• 2258-42-6 formyl acetic anhydride 
• 51384-34-0 dispiro-<1-methyl-3-oxoindoline-2,1'-(3,4-diphenylcyclobutane)-2',2''-(1-methyl-3-oxoindoline)> 
• 3260-63-7 1-methyl-1H-indol-3-yl acetate 
• 100-52-7 benzaldehyde 

Downstream Products

• 51384-34-0 dispiro-<1-methyl-3-oxoindoline-2,1'-(3,4-diphenylcyclobutane)-2',2''-(1-methyl-3-oxoindoline)> 
• 120670-23-7 (2-Methylamino-phenyl)-(5-phenyl-1H-[1,2,3]triazol-4-yl)-methanone 

Relevant articles and documents

A general and convenient palladium-catalyzed synthesis of benzylideneindolin-3-ones with formic acid as the CO source

A general and convenient palladium-catalyzed carbonylative synthesis of 2-benzylideneindolin-3-ones from 2-iodoanilines and arylacetylenes has been developed. With formic acid as the CO source and Ac2O as the activator, a variety of 2-benzylideneindolin-3-ones were obtained in good to excellent yields with exceptional functional group tolerance.

PHOTOISOMERIZATION OF α,β-UNSATURATED NITRO COMPOUNDS OF THE INDOLE SERIES TO ALKYLIDENE DERIVATIVES OF 2- AND 3-OXOINDOLINES

Under the influence of UV light the E isomers of 1-(2-indolyl)- and 1-(3-indolyl)-2-nitropropenes change into the Z isomers, which are then converted into the 2-hydroxyiminopropylidene derivatives of 2- and 3-oxoindoline.The 2-hydroxyimino-2-methoxycarbon