84713-51-9Relevant articles and documents
Aminolysis of Activated Esters Formed by Reaction of Carboxylate Salts with Strained Phosphonates and Phosphinates
Acher, Francine,Wakselman, Michel
, p. 3675 - 3676 (1982)
Nucleophilic attack of a carboxylate salt on a five membered phosphonic or phosphinic ester followed by an intramolecular acyl transfer reaction gives a substituted aryl ester.Due to the intramolecular base catalysis of a neighbouring P=O group the bimolecular aminolysis of this ester is a fast process.